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Frustrated Ising charge correlations in the kagome metal ScV6Sn6

S. J. Gomez Alvarado1, G. Pokharel1, B. R. Ortiz2, Joseph A. M. Paddison3, Suchismita Sarker4, J. P. C. Ruff4, and Stephen D. Wilson1

Phys. Rev. B 110, L140304 – Published 15 October, 2024

DOI: https://doi.org/10.1103/PhysRevB.110.L140304

Abstract

Here we resolve the real-space nature of the high-temperature, short-range charge correlations in the kagome metal ScV6Sn6. Diffuse scattering appears along a frustrated wave vector qH=(13,13,12) at temperatures far exceeding the charge order transition TCO=92 K, preempting long-range charge order with wave vectors along qK¯=(13,13,13). Using a combination of real space and reciprocal space analysis, we resolve the nature of the interactions between the primary out-of-plane Sc-Sn chain instability and the secondary strain-mediated distortion of the in-plane V kagome network. A minimal model of the diffuse scattering data reveals a high-temperature, short-ranged “zig-zag” phase of in-plane correlations that maps to a frustrated triangular lattice Ising model with antiferromagnetic interactions and provides a real-space understanding of the origin of frustrated charge order in this material.

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