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  • Letter

Nonanalytic magnetic response and intrinsic ferromagnetic clusters in a kagome spin-liquid candidate

B. S. Shivaram1,*, Joseph C. Prestigiacomo2, Aini Xu3, Zhenyuan Zeng3,4, Trevor D. Ford1, Itamar Kimchi5, Shiliang Li3,4,6, and Patrick A. Lee7,†

  • *Contact author: bss2d@virginia.edu
  • †Contact author: palee@mit.edu

Phys. Rev. B 110, L121105 – Published 11 September, 2024

DOI: https://doi.org/10.1103/PhysRevB.110.L121105

Abstract

Finding distinct signatures of a quantum spin liquid (QSL) is an ongoing quest in condensed matter physics, invariably complicated by the presence of disorder in real materials. In this regard the two-dimensional kagome system YCu3(OH)6[(ClxBr(1−x))3−y(OH)y] (YCOB−Cl), where the vast mismatch in size of Y and Cu avoids substitutional disorder, otherwise present in kagome materials, has emerged as a favorable candidate. In crystals of this system, with x<0.4 and no long-range order, we report an unusual field-dependent magnetization M(B), where M/B changes linearly with |B|, the absolute value of the field, in contrast to the expected quadratic behavior. Model calculations with a distribution of ferromagnetic (FM) clusters faithfully capture the observed features. YCOB-Cl exhibits a field-enhanced T2 heat capacity expected in certain spin-liquid models. However, a concomitant linear T behavior in the spin susceptibility has been lacking. Our work suggests that FM clusters, by dominating the contribution to the susceptibility, mask the true underlying behavior.

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