The electronic structure of the topmost layer in ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$ in the close vicinity of the Fermi level is investigated by angle-resolved photoemission spectroscopy with a 7-eV laser. We find that the spin-orbit coupling (SOC) predicted as 100 meV by the density functional theory calculations is enormously enhanced in a real material up to 250 meV, even more than that of bulk state (200 meV), by the electron-correlation effect increased by the octahedral rotation in the crystal structure. This causes the formation of highly orbital-mixing small Fermi pockets and reasonably explains why the orbital-selective Mott transition is not realized in perovskite oxides with crystal distortion. Interestingly, Hund's metal feature allows the quasiparticle generation only near $E_{\mathrm{F}}$, restricting the spectral gap opening derived by band hybridization within an extremely small binding energy ($<$ 10 meV). Furthermore, it causes coherent-incoherent crossover, making the Fermi pockets disappear at elevated temperatures. The anomalous Fermi pockets are characterized by the dichotomy of the orbital-isolating Hund's coupling and the orbital-mixing SOC, which is key to understanding the nature of ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$.

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• Electrical properties
• Fermi surface
• Ruthenates
• Strongly correlated systems
• Angle-resolved photoemission spectroscopy