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  • Letter

Hidden excitonic quantum states with broken time-reversal symmetry

Giacomo Mazza1,2,* and Marco Polini1,3,4

  • 1Dipartimento di Fisica dell'Università di Pisa, Largo Bruno Pontecorvo 3, I-56127 Pisa, Italy
  • 2Department of Quantum Matter Physics, University of Geneva, Quai Ernest-Ansermet 24, 1211 Geneva, Switzerland
  • 3Istituto Italiano di Tecnologia, Graphene Labs, Via Morego 30, I-16163 Genova, Italy
  • 4ICFO-Institut de Ciències Fotòniques, The Barcelona Institute of Science and Technology, Av. Carl Friedrich Gauss 3, 08860 Castelldefels (Barcelona), Spain

  • *giacomo.mazza@unipi.it

Phys. Rev. B 108, L241107 – Published 12 December, 2023

DOI: https://doi.org/10.1103/PhysRevB.108.L241107

Abstract

The spontaneous breaking of time-reversal symmetry due to purely orbital mechanisms (i.e., not involving spin degrees of freedom) yields extremely exotic phases of matter such as Chern insulators and chiral superconductors. In this Letter, we show that excitonic insulators, by exploiting the transition from the excitonic ground state to a purely orbital time-reversal symmetry broken hidden state, can realize another notable example of this class. The transition to the hidden state is controlled by engineered geometrical constraints, which enable the coupling between the excitonic order parameter and the free-space electromagnetic field. These results pave the way towards exotic orbital magnetic order in quantum materials and are also relevant for disentangling excitonic phase transitions from trivial structural ones.

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