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Phonon-mediated s-wave superconductivity in the kagome metal CsV3Sb5 under pressure

Chongze Wang1,2, Yu Jia1,3, Zhenyu Zhang4, and Jun-Hyung Cho2,*

  • 1Joint Center for Theoretical Physics, School of Physics and Electronics, Henan University, Kaifeng 475004, People's Republic of China
  • 2Department of Physics and Research Institute for Natural Science, Hanyang University, 222 Wangsimni-ro, Seongdong-Ku, Seoul 04763, Republic of Korea
  • 3Key Laboratory for Special Functional Materials of the Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China
  • 4International Center for Quantum Design of Functional Materials (ICQD), Hefei National Laboratory for Physical Sciences at Microscale, and Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei 230026, China

  • *Corresponding author: chojh@hanyang.ac.kr

Phys. Rev. B 108, L060503 – Published 11 August, 2023

DOI: https://doi.org/10.1103/PhysRevB.108.L060503

Abstract

The nature of the superconducting pairing state in the pristine phase of the compressed kagome metal CsV3Sb5 under pressure is studied by the Migdal-Eliashberg formalism and density-functional theory calculations. We find that the superconducting gap distribution driven by electron-phonon coupling is anisotropic and nodeless. It is revealed that the V 3d and Sb 5p orbitals forming the four Fermi surface sheets are strongly coupled to the V-V bond-stretching and V-Sb bond-bending phonon modes. The resultant superconducting gaps associated with V 3dxy,x2−y2,z2 and 3dxz,yz orbitals is larger in their average magnitude and more widely spread compared to that associated with the Sb 5pz orbital. Meanwhile, we find that unconventional superconductivity driven by electron correlation effects is unlikely because the saddle points at the M point near the Fermi level do not generate van Hove singularities in the total density of states. Our findings demonstrate that the superconductivity of compressed CsV3Sb5 can be explained by the anisotropic multiband pairing mechanism with conventional phonon-mediated s-wave symmetry, evidenced by recent experimental observations at ambient pressure and under pressure.

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