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  • Letter

Hidden Zeeman-type spin polarization in bulk crystals

Shan Guan1, Jun-Wei Luo1,2,*, Shu-Shen Li1,2, and Alex Zunger3

  • 1State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
  • 2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • 3Renewable and Sustainable Energy Institute, University of Colorado, Boulder, Colorado 80309, USA

  • *jwluo@semi.ac.cn

Phys. Rev. B 107, L081201 – Published 7 February, 2023

DOI: https://doi.org/10.1103/PhysRevB.107.L081201

Abstract

Exploring hidden effects that have been overlooked given the nominal global crystal symmetry but are indeed visible in solid-state materials has been a fascinating subject of research recently. Here, we introduce a hidden Zeeman-type spin polarization (HZSP) in nonmagnetic bulk crystals with sublattice structures. In the momentum space of these crystals, the doubly degenerate bands formed in a certain plane can exhibit a uniform spin configuration with opposite spin orientations perpendicular to this plane, whereas such degenerate states are spatially separated in a pair of real-space sectors. Interestingly, we find that HZSP can manifest itself in both centrosymmetric and noncentrosymmetric materials. We further demonstrate the important role of nonsymmorphic twofold screw-rotational symmetry played in the formation of HZSP. Moreover, two representative material examples, i.e., centrosymmetric WSe2 and noncentrosymmetric BaBi4O7, are identified to show HZSP via first-principles calculations. Our finding thus not only opens different perspectives for hidden spin polarization research but also significantly broadens the range of materials towards spintronics applications.

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