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H2 superglass on an amorphous carbon substrate

M. C. Gordillo

J. Boronat

  • Departamento de Sistemas Físicos, Químicos y Naturales, Universidad Pablo de Olavide, Carretera de Utrera km 1, E-41013 Sevilla, Spain and Instituto Carlos I de Física Teórica y Computacional, Universidad de Granada, E-18071 Granada, Spain

  • Departament de Física, Universitat Politècnica de Catalunya, Campus Nord B4-B5, E-08034 Barcelona, Spain

Phys. Rev. B 107, L060505 – Published 23 February, 2023

DOI: https://doi.org/10.1103/PhysRevB.107.L060505

Abstract

The phase diagram of a para-H2 monolayer absorbed on an experimentally synthesized amorphous carbon sheet was calculated using a diffusion Monte Carlo technique. We found that the ground state of that system changed drastically from a perfectly flat substrate to a situation in which the carbon atoms were allowed a certain degree of disorder in the z direction. In the first case, at zero pressure we have a glass of density 0.056±0.003 Å−2 in equilibrium with an incommensurate solid of 0.068±0.002 Å−2. At the equilibrium density, the glass was found to have a tiny, but non-negligible superfluid fraction of less than 1% (0.44±0.05%). In the z-disordered substrate, we observe a significant enhancement of the superfluid fraction in the glass phase as well as a smaller but not zero value in the incommensurate crystal.

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