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Charge order with unusual star-of-David lattice in monolayer NbTe2

Taiki Taguchi1, Katsuaki Sugawara1,2,3,4, Hirofumi Oka2, Tappei Kawakami1, Yasuaki Saruta1, Takemi Kato1, Kosuke Nakayama1,4, Seigo Souma2,3, Takashi Takahashi1,2,3 et al.

Tomoteru Fukumura2,3,5 and Takafumi Sato1,2,3,6

  • 1Department of Physics, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
  • 2Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan
  • 3Center for Science and Innovation in Spintronics (CSIS), Tohoku University, Sendai 980-8577, Japan
  • 4Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), Tokyo 102-0076, Japan
  • 5Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
  • 6International Center for Synchrotron Radiation Innovation Smart (SRIS), Tohoku University, Sendai 980-8577, Japan

Phys. Rev. B 107, L041105 – Published 17 January, 2023

DOI: https://doi.org/10.1103/PhysRevB.107.L041105

Abstract

Interplay between fermiology and electron correlation is crucial for realizing exotic quantum phases. Transition-metal dichalcogenide (TMD) 1T−TaS2 has sparked tremendous attention owing to its unique Mott-insulating phase coexisting with the charge-density wave (CDW). However, how the fermiology and electron correlation are associated with such properties has yet to be clarified. Here we demonstrate that monolayer 1T−NbTe2 is a new class of two-dimensional TMD which has the star-of-David lattice similarly to bulk TaS2 and isostructural monolayer NbSe2, but exhibits a metallic ground state with an unusual lattice periodicity (19×19) characterized by the sparsely occupied star-of-David lattice. By using angle-resolved photoemission and scanning-tunneling spectroscopies in combination with first-principles band-structure calculations, we found that the hidden Fermi-surface nesting and associated CDW formation are a primary cause to realize this unique correlated metallic state with no signature of Mott gap. The present result points to a vital role of underlying fermiology to characterize the Mott phase of TMDs.

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