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Heat transport of the kagome Heisenberg quantum spin liquid candidate YCu3(OH)6.5Br2.5: Localized magnetic excitations and a putative spin gap

Xiaochen Hong1,2,*, Mahdi Behnami2, Long Yuan3, Boqiang Li3, Wolfram Brenig4, Bernd Büchner2,5, Yuesheng Li3,†, and Christian Hess1,2,‡

  • 1Fakultät für Mathematik und Naturwissenschaften, Bergische Universität Wuppertal, 42097 Wuppertal, Germany
  • 2Leibniz-Institute for Solid State and Materials Research (IFW-Dresden), 01069 Dresden, Germany
  • 3Wuhan National High Magnetic Field Center and School of Physics, Huazhong University of Science and Technology, 430074 Wuhan, China
  • 4Institute for Theoretical Physics, TU Braunschweig, 38106 Braunschweig, Germany
  • 5Institute of Solid State and Materials Physics and Würzburg-Dresden Cluster of Excellence ct.qmat, Technische Universität Dresden, 01062 Dresden, Germany

  • *xhong@uni-wuppertal.de
  • †yuesheng_li@hust.edu.cn
  • ‡c.hess@uni-wuppertal.de

Phys. Rev. B 106, L220406 – Published 19 December, 2022

DOI: https://doi.org/10.1103/PhysRevB.106.L220406

Abstract

The spin-1/2 kagome Heisenberg antiferromagnet is generally accepted as one of the most promising two-dimensional models to realize a quantum spin liquid state. Previous experimental efforts were almost exclusively on only one archetypal material, the herbertsmithite ZnCu3(OH)6Cl2, which unfortunately suffers from the notorious orphan spin problem caused by magnetic disorders. Here, we turn to YCu3(OH)6.5Br2.5, recently recognized as another host of a globally undistorted kagome Cu2+ lattice free from orphan spins, and thus a more feasible system for studying the intrinsic kagome quantum spin liquid physics. Our high-resolution low-temperature thermal conductivity measurements yield a vanishingly small residual linear term of κ/T (T→0), and thus clearly rule out itinerant gapless fermionic excitations. An unusual scattering of phonons grows exponentially with temperature, suggesting thermally activated phonon-spin scattering and hence a gapped magnetic excitation, consistent with a Z2 quantum spin liquid ground state. Additionally, an analysis of the magnetic field impact on the thermal conductivity reveals a field closing of the spin gap, while the excitations remain localized.

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