Two-dimensional (2D) Stiefel-Whitney (SW) insulator (SWI) is a fragile topological state characterized by the second SW class in the presence of space-time inversion symmetry. So far, SWIs have been proposed in several electronic materials but seldom in phononic systems. Here we recognize that a large class of 2D buckled honeycomb crystals termed Xenes and their ligand-functionalized derivatives realize the nontrivial phononic SW topology. The phononic SWIs are identified by a nonzero second SW number $w_2=1$, associated with gaped edge states and robust topological corner modes. Despite the versatility of electronic topological properties in these materials, the nontrivial phononic SW topology is mainly attributed to the double band inversion between in-plane acoustic and out-of-plane optical bands with opposite parities due to the structural buckling of the honeycomb lattice. Our findings not only reveal an overlooked phononic topological property of 2D Xene-related materials, but also afford abundant readily synthesizable material candidates with simple phononic spectra for further experimental studies of phononic SW topology physics.

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• Phonons
• Topological phases of matter
• 2-dimensional systems
• Germanene
• Phosphorene
• Silicene
• Stanene
• First-principles calculations