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Niobium in the clean limit: An intrinsic type-I superconductor

Ruslan Prozorov1,2,*, Mehdi Zarea3, and James A. Sauls4

  • 1Ames National Laboratory, Ames, Iowa 50011, USA
  • 2Department of Physics & Astronomy, Iowa State University, Ames, Iowa 50011, USA
  • 3Center for Applied Physics and Superconducting Technologies, Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208, USA
  • 4Hearne Institute of Theoretical Physics, Department of Physics & Astronomy, Louisiana State University, Baton Rouge, LA 70803, USA

  • *prozorov@ameslab.gov

Phys. Rev. B 106, L180505 – Published 17 November, 2022

DOI: https://doi.org/10.1103/PhysRevB.106.L180505

Abstract

Niobium is one of the most researched superconductors, both theoretically and experimentally. It is enormously significant in all branches of superconducting applications, from powerful magnets to quantum computing. It is therefore imperative to understand its fundamental properties in great detail. Here, we use the results of recent microscopic calculations of anisotropic electronic, phonon, and superconducting properties, and apply a thermodynamic criterion for the type of superconductivity, more accurate and straightforward than a conventional Ginzburg-Landau parameter κ-based delineation, to show that pure niobium is a type-I superconductor in the clean limit. However, disorder (impurities, defects, strain, stress) pushes it to become a type-II superconductor.

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