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Unraveling the origin of the peculiar transition in the magnetically ordered phase of the Weyl semimetal Co3Sn2S2

Ivica Živković1,*, Ravi Yadav2, Jian-Rui Soh1, ChangJiang Yi3,4, YouGuo Shi4,5,6, Oleg V. Yazyev2, and Henrik M. Rønnow1

  • 1Laboratory for Quantum Magnetism, Institute of Physics, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland
  • 2Institute of Physics, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland
  • 3Department of Solid State Chemistry, Max Planck Institute for Chemical Physics of Solids, D-01187 Dresden, Germany
  • 4Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • 5School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, China
  • 6Songshan Lake Materials Laboratory, Dongguan 523808, China

  • *ivica.zivkovic@epfl.ch

Phys. Rev. B 106, L180403 – Published 21 November, 2022

DOI: https://doi.org/10.1103/PhysRevB.106.L180403

Abstract

The recent discovery of topologically nontrivial behavior in Co3Sn2S2 stimulated a notable interest in this itinerant ferromagnet (TC=174 K). The exact magnetic state remains ambiguous, with several reports indicating the existence of a second transition in the range 125–130 K, with antiferromagnetic and glassy phases proposed to coexist with the ferromagnetic phase. Using detailed angle-dependent dc and ac magnetization measurements on large, high-quality single crystals we reveal a highly anisotropic behavior of both the static and dynamic response of Co3Sn2S2. It is established that many observations related to sharp magnetization changes when B∥c are influenced by the demagnetization factor of a sample. On the other hand, a genuine transition has been found at TP=128 K, with the magnetic response being strictly perpendicular to the c axis and several orders of magnitude smaller than for B∥c. Calculations using density-functional theory indicate that the ground state magnetic structure consist of magnetic moments canted away from the c axis by a small angle (∼1.5∘). We argue that the second transition originates from a small additional canting of moments within the kagome plane, with two equivalent orientations for each spin.

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