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Ground state of Ce3Bi4Pd3 unraveled by hydrostatic pressure

M. O. Ajeesh1, S. M. Thomas1, S. K. Kushwaha2, E. D. Bauer1, F. Ronning1, J. D. Thompson1, N. Harrison2, and P. F. S. Rosa1

  • 1Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
  • 2National High Magnetic Field Laboratory, Los Alamos, New Mexico 87545, USA

Phys. Rev. B 106, L161105 – Published 10 October, 2022

DOI: https://doi.org/10.1103/PhysRevB.106.L161105

Abstract

Noncentrosymmetric Ce3Bi4Pd3 has attracted a lot of attention as a candidate for strongly correlated topological material, yet its experimental ground state remains a matter of contention. Two conflicting scenarios have emerged from a comparison to the prototypical Kondo insulator Ce3Bi4Pt3: Either Ce3Bi4Pd3 is a spin-orbit-driven topological semimetal or a Kondo insulator with smaller Kondo coupling than its Pt counterpart. Here, we determine the ground state of Ce3Bi4Pd3 via electrical resistivity measurements under hydrostatic pressure, which is a clean symmetry-preserving tuning parameter that increases hybridization but virtually preserves spin-orbit coupling. Ce3Bi4Pd3 becomes more insulating under pressures up to 2.3 GPa, which is a signature of Ce-based Kondo insulating materials in the considered pressure range. Its small zero-pressure gap increases quadratically with pressure, similar to the behavior observed in the series Ce3Bi4(Pt1−xPdx)3, which indicates that Pt substitution and applied pressure have a similar effect. Our result not only demonstrates that Kondo coupling, rather than spin-orbit coupling, is the main tuning parameter in this class of materials, but it also establishes that Ce3Bi4Pd3 has a narrow-gap Kondo insulating ground state.

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