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  • Letter

Thermodynamic signature of SU(4) spin-orbital liquid and symmetry fractionalization from Lieb-Schultz-Mattis theorem

Masahiko G. Yamada1,* and Satoshi Fujimoto1,2

  • 1Department of Materials Engineering Science, Osaka University, Toyonaka 560-8531, Japan
  • 2Center for Quantum Information and Quantum Biology, Osaka University, Toyonaka 560-8531, Japan

  • *myamada@mp.es.osaka-u.ac.jp

Phys. Rev. B 105, L201115 – Published 31 May, 2022

DOI: https://doi.org/10.1103/PhysRevB.105.L201115

Abstract

The SU(4) Heisenberg model on a honeycomb lattice is expected to host a quantum spin-orbital liquid at low temperature with a surprising candidate material, α−ZrCl3. We employed the canonical thermal pure quantum state method to investigate the finite-temperature phase of this model. Exploiting the full symmetry of SU(4), calculation up to a 24-site cluster, which is equivalent to 48 sites in the spin-12 language, is possible. This state-of-the-art computation with large-scale parallelization enables us to capture the thermodynamic properties of the SU(4) Heisenberg model on a honeycomb lattice. In particular, the specific heat shows a characteristic peak-and-shoulder structure, which should be related to the nature of the low-temperature quantum spin-orbital liquid phase. We also discuss what can be concluded from the assumption that the ground state is gapped and symmetric in view of the generalized Lieb-Schultz-Mattis theorem.

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