Recently, superconductivity has been discovered in rocksalt-structured binary lanthanum monoxide LaO through state-of-the-art oxide thin-film epitaxy. In this work, we reveal that the normal state of superconducting LaO is a ${\mathbb{Z}}_2$ nontrivial topological metal, where the Dirac point protected by the crystal symmetry is located around the Fermi energy. By analyzing the orbital characteristics, we show that the nature of the topological band structure of LaO originates from the intra-atomic transition from the outer shell La $5d$ to the inner shell $4f$ orbitals driven by the strong octahedral crystal field. Furthermore, the appearance of novel surface states unambiguously demonstrates the topological signature of the LaO superconductor. Our theoretical findings not only shed light on the understanding of the exotic quantum behaviors in the LaO superconductor with intimate correlation between $4f$ and $5d$ orbitals in La, but also provide an exciting platform to explore the interplay between nontrivial topology and superconductivity.

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• Electronic structure
• Impurities in superconductors
• Superconducting phase transition
• Dirac semimetal
• Low-temperature superconductors
• Oxides
• Density functional calculations
• Methods in superconductivity