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  • Letter

Failed excitonic quantum phase transition in Ta2Ni(Se1−xSx)5

Pavel A. Volkov1,*, Mai Ye1,†, Himanshu Lohani2, Irena Feldman2, Amit Kanigel2, and Girsh Blumberg1,3,‡

  • 1Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854, USA
  • 2Department of Physics, Technion - Israel Institute of Technology, Haifa 32000, Israel
  • 3National Institute of Chemical Physics and Biophysics, 12618 Tallinn, Estonia

  • *pv184@physics.rutgers.edu
  • †mye@physics.rutgers.edu
  • ‡girsh@physics.rutgers.edu

Phys. Rev. B 104, L241103 – Published 10 December, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L241103

Abstract

We study the electronic phase diagram of the excitonic insulator candidates Ta2Ni(Se1−xSx)5 (x=0,⋯,1) using polarization resolved Raman spectroscopy. Critical excitonic fluctuations are observed that diminish with x and ultimately shift to high energies, characteristic of a quantum phase transition. Nonetheless, a symmetry-breaking transition at finite temperatures is detected for all x, exposing a cooperating lattice instability that takes over for large x. Our study reveals a failed excitonic quantum phase transition, masked by a preemptive structural order.

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