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Pinwheel valence bond crystal ground state of the spin-12 Heisenberg antiferromagnet on the shuriken lattice

Nikita Astrakhantsev1,2,*, Francesco Ferrari3,*, Nils Niggemann4,*, Tobias Müller5, Aishwarya Chauhan6, Augustine Kshetrimayum4,7, Pratyay Ghosh5, Nicolas Regnault8, Ronny Thomale5,6 et al.

Johannes Reuther4,7, Titus Neupert1, and Yasir Iqbal6,†

  • 1Department of Physics, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland
  • 2Institute for Theoretical and Experimental Physics (ITEP), Moscow 117218, Russia
  • 3Institut für Theoretische Physik, Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, D-60438 Frankfurt am Main, Germany
  • 4Dahlem Center for Complex Quantum Systems and Institut für Theoretische Physik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany
  • 5Institut für Theoretische Physik und Astrophysik, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
  • 6Department of Physics and Quantum Centers in Diamond and Emerging Materials (QuCenDiEM) group, Indian Institute of Technology Madras, Chennai 600036, India
  • 7Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, D-14109 Berlin, Germany
  • 8Joseph Henry Laboratories and Department of Physics, Princeton University, Princeton, New Jersey 08544, USA

  • *These authors contributed equally to this work.
  • †yiqbal@physics.iitm.ac.in

Phys. Rev. B 104, L220408 – Published 22 December, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L220408

Abstract

We investigate the nature of the ground state of the spin-12 Heisenberg antiferromagnet on the shuriken lattice by complementary state-of-the-art numerical techniques, such as variational Monte Carlo (VMC) with versatile Gutzwiller-projected Jastrow wave functions, unconstrained multivariable variational Monte Carlo (mVMC), and pseudofermion/pseudo-Majorana functional renormalization group (PFFRG/PMFRG) methods. We establish the presence of a quantum paramagnetic ground state and investigate its nature, by classifying symmetric and chiral quantum spin liquids, and inspecting their instabilities towards competing valence bond crystal (VBC) orders. Our VMC analysis reveals that a VBC with a pinwheel structure emerges as the lowest-energy variational ground state, and it is obtained as an instability of the U(1) Dirac spin liquid. Analogous conclusions are drawn from mVMC calculations employing accurate BCS pairing states supplemented by symmetry projectors, which confirm the presence of pinwheel VBC order by a thorough analysis of dimer-dimer correlation functions. Our work highlights the nontrivial role of quantum fluctuations via the Gutzwiller projector in resolving the subtle interplay between competing orders.

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