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Suppressed incommensurate order in swedenborgite Ca0.5Y0.5BaCo4O7

Shang Gao1,2,3,*, Vilmos Kocsis3,†, Minoru Soda3,4, Feng Ye1, Yaohua Liu1, Andrew F. May2, Yasujiro Taguchi3, Yoshinori Tokura3,5, Taka-hisa Arima3,6 et al.

Werner Schweika7,8, Andrew D. Christianson2, and Matthew B. Stone1

  • 1Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
  • 2Materials Science & Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
  • 3RIKEN Center for Emergent Matter Science (CEMS), Wako 351-0198, Japan
  • 4Department of Physics, Advanced Sciences, GSHS, Ochanomizu University, Tokyo 112-8610, Japan
  • 5Department of Applied Physics and Tokyo College, University of Tokyo, Tokyo 113-8656, Japan
  • 6Department of Advanced Materials Science, University of Tokyo, Kashiwa 277-8561, Japan
  • 7Jülich Center for Neutron Science JCNS and Peter Grünberg Institute PGI, JARA-FIT, Forschungszentrum Jülich, Jülich 52425, Germany
  • 8European Spallation Source ESS ERIC, Lund 22100, Sweden

  • *gaos2@ornl.gov
  • †Present address: Institut für Festkörperforschung, Leibniz IFW Dresden, 01069 Dresden, Germany.

Phys. Rev. B 104, L140408 – Published 18 October, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L140408

Abstract

Swedenborgite Ca0.5Y0.5BaCo4O7 (CYBCO) with geometrically frustrated kagome and triangular lattices exhibits a disordered ground state in spite of strong antiferromagnetic couplings between the Co spins. The character of the disordered state has been debated due to ambiguous Co states in the triangular layers. Here, we perform single-crystal diffuse neutron scattering experiments to fully characterize the short-range spin correlations in CYBCO. Through reverse Monte Carlo and self-consistent Gaussian approximation analyses, we confirm that the Co ions in both the kagome and triangular layers are magnetic, and the interlayer couplings, together with the lattice distortion, promote an incommensurate magnetic order that is suppressed possibly by exchange disorder. Our work clarifies the short-range spin correlations in CYBCO and establishes a general correspondence between unequal interactions and incommensurate spin correlations on the swedenborgite lattice.

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