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Origin of the different electronic structure of Rh- and Ru-doped Sr2IrO4

Véronique Brouet1, Paul Foulquier1,2, Alex Louat1, François Bertran3, Patrick Le Fèvre3, Julien E. Rault3, and Dorothée Colson2

  • 1Université Paris-Saclay, CNRS, Laboratoire de Physique des Solides, 91405 Orsay, France
  • 2Université Paris-Saclay, CEA, CNRS, SPEC, 91191 Gif-sur-Yvette, France
  • 3Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin-BP 48, 91192 Gif sur Yvette, France

Phys. Rev. B 104, L121104 – Published 3 September, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L121104

Abstract

One way to induce insulator-to-metal transitions in the spin-orbit Mott insulator Sr2IrO4 is to substitute iridium with transition metals (Ru, Rh). However, this creates intriguing inhomogeneous metallic states, which cannot be described by a simple doping effect. We detail the electronic structure of the Ru-doped case with angle-resolved photoemission and show that, in contrast to Rh, it cannot be connected to the undoped case by a rigid shift. We further identify bands below EF coexisting with the metallic ones that we assign to nonbonding Ir sites. We rationalize the differences between Rh and Ru by a different hybridization with oxygen, which mediates the coupling to Ir and sensitively affects the effective doping. We argue that the spin-orbit coupling does not control either the charge transfer or the transition threshold.

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