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Quantum size effects in the magnetic susceptibility of a metallic nanoparticle

M. Roda-Llordes1,2,*, C. Gonzalez-Ballestero1,2, A. E. Rubio López1,2, M. J. Martínez-Pérez3,4, F. Luis3, and O. Romero-Isart1,2,†

  • 1Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck, Austria
  • 2Institute for Theoretical Physics, University of Innsbruck, A-6020 Innsbruck, Austria
  • 3Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, E-50009 Zaragoza, Spain
  • 4Fundación ARAID, Avda. de Ranillas, E-50018 Zaragoza, Spain

  • *marc.roda-llordes@uibk.ac.at
  • †oriol.romero-isart@uibk.ac.at

Phys. Rev. B 104, L100407 – Published 10 September, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L100407

Abstract

We theoretically study quantum size effects in the magnetic response of a spherical metallic nanoparticle (e.g., gold). Using the jellium model in spherical coordinates, we compute the induced magnetic moment and the magnetic susceptibility for a nanoparticle in the presence of a static external magnetic field. Below a critical magnetic field the magnetic response is diamagnetic, whereas above such field the magnetization is characterized by sharp, steplike increases of several tenths of Bohr magnetons, associated with the Zeeman crossing of energy levels above and below the Fermi sea. We quantify the robustness of these regimes against thermal excitations and finite linewidth of the electronic levels. Finally, we propose two methods for experimental detection of the quantum size effects based on the coupling to superconducting quantum interference devices.

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