- Letter
Pitfalls and solutions for perovskite transparent conductors
Phys. Rev. B 104, L041112 – Published 28 July, 2021
DOI: https://doi.org/10.1103/PhysRevB.104.L041112
Abstract
Transparent conductors—nearly an oxymoron—are in pressing demand, as ultrathin-film technologies become ubiquitous commodities. With current solutions relying on nonabundant elements, it has recently been suggested that perovskites—such as and —could serve as next generation transparent conductors. In these, strong electronic correlations push the plasma frequency below the visible spectrum to curtail absorption. Our ab initio calculations and analytical insights establish, however, that the required effective mass enhancement unavoidably comes at a price: An increased scattering that causes substantial optical absorption above the plasma edge. We circumvent this dilemma and identify high-grade perovskite transparent conductors, relying on an interplay of hole doping, larger bandwidths, separation of bands, but only mild mass enhancements.