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Pitfalls and solutions for perovskite transparent conductors

Liang Si1,2, Josef Kaufmann2, Zhicheng Zhong1,3,*, Jan M. Tomczak2, and Karsten Held2,†

  • 1Key Laboratory of Magnetic Materials and Devices & Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences, Ningbo 315201, China
  • 2Institute of Solid State Physics, Vienna University of Technology, 1040 Vienna, Austria
  • 3China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

  • *zhong@nimte.ac.cn
  • †held@ifp.tuwien.ac.at

Phys. Rev. B 104, L041112 – Published 28 July, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L041112

Abstract

Transparent conductors—nearly an oxymoron—are in pressing demand, as ultrathin-film technologies become ubiquitous commodities. With current solutions relying on nonabundant elements, it has recently been suggested that perovskites—such as SrVO3 and SrNbO3—could serve as next generation transparent conductors. In these, strong electronic correlations push the plasma frequency below the visible spectrum to curtail absorption. Our ab initio calculations and analytical insights establish, however, that the required effective mass enhancement unavoidably comes at a price: An increased scattering that causes substantial optical absorption above the plasma edge. We circumvent this dilemma and identify high-grade perovskite transparent conductors, relying on an interplay of hole doping, larger bandwidths, separation of bands, but only mild mass enhancements.

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