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Two-dimensional ferromagnetic spin-orbital excitations in honeycomb VI3

H. Lane1,2,3, E. Pachoud2, J. A. Rodriguez-Rivera4,5, M. Songvilay1, G. Xu4, P. M. Gehring4, J. P. Attfield2, R. A. Ewings3, and C. Stock1

  • 1School of Physics and Astronomy, University of Edinburgh, Edinburgh EH9 3JZ, United Kingdom
  • 2School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, Edinburgh EH9 3FJ, United Kingdom
  • 3ISIS Pulsed Neutron and Muon Source, STFC Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxon OX11 0QX, United Kingdom
  • 4NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
  • 5Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, USA

Phys. Rev. B 104, L020411 – Published 20 July, 2021

DOI: https://doi.org/10.1103/PhysRevB.104.L020411

Abstract

VI3 is a ferromagnet with planar honeycomb sheets of bonded V3+ ions held together by van der Waals forces. We apply neutron spectroscopy to measure the two-dimensional (J/Jc≈17) magnetic excitations in the ferromagnetic phase, finding two energetically gapped (Δ≈kBTc≈55K) and dispersive excitations. We apply a multilevel spin-wave formalism to describe the spectra in terms of two coexisting domains hosting differing V3+ orbital ground states built from contrasting distorted octahedral environments. This analysis fits a common nearest-neighbor in-plane exchange coupling (J=−8.6±0.3meV) between V3+ sites. The distorted local crystalline electric field combined with spin-orbit coupling provides the needed magnetic anisotropy for spatially long-ranged two-dimensional ferromagnetism in VI3.

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