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Fluctuation-induced interactions and the spin-glass transition in Fe2TiO5

P. G. LaBarre1, D. Phelan2, Y. Xin3, F. Ye4, T. Besara3,5, T. Siegrist3,5, S. V. Syzranov1, S. Rosenkranz2, and A. P. Ramirez1

  • 1Physics Department, University of California Santa Cruz, Santa Cruz, California 95064, USA
  • 2Materials Science Division, Argonne National Laboratory, Lemont, Illinois 60439, USA
  • 3NHMFL, Florida State University, Tallahassee, Florida 32310, USA
  • 4Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, USA
  • 5Department of Chemical and Biomedical Engineering, FAMU-FSU College of Engineering, Tallahassee, Florida 32310, USA

Phys. Rev. B 103, L220404 – Published 11 June, 2021

DOI: https://doi.org/10.1103/PhysRevB.103.L220404

Abstract

We investigate the spin-glass transition in the strongly frustrated well-known compound Fe2TiO5. A remarkable feature of this transition, widely discussed in the literature, is its anisotropic properties: The transition manifests itself in the magnetic susceptibly only along one axis, despite Fe3+ d5 spins having no orbital component. We demonstrate, using neutron scattering, that below the transition temperature Tg=55 K, Fe2TiO5 develops nanoscale surfboard-shaped antiferromagnetic regions in which the Fe3+ spins are aligned perpendicular to the axis which exhibits freezing. We show that the glass transition may result from the freezing of transverse fluctuations of the magnetization of these regions and we develop a mean-field replica theory of such a transition, revealing a type of magnetic van der Waals effect.

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Corrections

22 June, 2021

Correction: The surname of the fifth author contained an error and has been fixed.

20 July, 2021

Second Correction: The omission of an acknowledgment statement has been fixed.

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