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  • Letter

Perturbative approach to the polaron shift of excitons in transition metal dichalcogenides

J. C. G. Henriques and N. M. R. Peres

  • Department and Centre of Physics, and QuantaLab, University of Minho, Campus of Gualtar, 4710-057 Braga, Portugal and International Iberian Nanotechnology Laboratory (INL), Av. Mestre José Veiga, 4715-330 Braga, Portugal

Phys. Rev. B 103, L161402 – Published 2 April, 2021

DOI: https://doi.org/10.1103/PhysRevB.103.L161402

Abstract

In this Letter, we study the effect of phonons on the position of the 1s excitonic resonance of the fundamental absorption transition line in two-dimensional transition metal dichalcogenides. We apply our theory to WS2, a two-dimensional material where the shift in the absorption peak position has been measured as a function of temperature. The theory is composed of two ingredients only: (i) the effect of longitudinal optical phonons on the absorption peak position, which we describe with second-order perturbation theory, and (ii) the effect of phonons on the value of the single-particle energy gap, which we describe with the Huang Rhys model. Our results show excellent agreement with the experimentally measured shift of the absorption peak with the temperature.

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