- Letter
Collective excitations in the tetravalent lanthanide honeycomb antiferromagnet
Phys. Rev. B 103, L121109 – Published 12 March, 2021
DOI: https://doi.org/10.1103/PhysRevB.103.L121109
Abstract
Thermomagnetic and inelastic neutron-scattering measurements on are reported. This material is an antiferromagnetic honeycomb magnet based on the tetravalent lanthanide and has been proposed to host dominant antiferromagnetic Kitaev interactions. These measurements reveal magnetic fluctuations in below an energy of 2 meV as well as crystal-field excitations around 230 meV. The latter energy is comparable to the scale of the spin-orbit interaction and explains both the very small effective moment of around per and the difficulty to uncover any static magnetic scattering below the ordering transition at 4.6 K. By comparing the low-energy magnetic excitations in to those of the isostructural spin-only compound, , a microscopic model of exchange interactions is developed that implicates dominant and surprisingly large Heisenberg exchange interactions meV. Although antiferromagnetic Kitaev interactions with cannot be excluded, the inelastic neutron-scattering data of is best explained with a easy-axis XXZ exchange anisotropy.