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    Quantum-optical theory of the few-femtosecond nonlinear optical response of Drude metals with a nonparabolic conduction band

    Ieng-Wai Un*

    Subhajit Sarkar

    Yonatan Sivan

    • Key Laboratory of Atomic and Subatomic Structure and Quantum Control (Ministry of Education), Guangdong Basic Research Center of Excellence for Structure and Fundamental Interactions of Matter, School of Physics, South China Normal University, Guangzhou 510006, China and Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, Guangdong-Hong Kong Joint Laboratory of Quantum Matter, South China Normal University, Guangzhou 510006, China

    • *Contact author: iengwai@m.scnu.edu.cn

    Phys. Rev. B 113, 165411 – Published 13 April, 2026

    DOI: https://doi.org/10.1103/9rs8-8zh8

    Abstract

    We develop an energy-space density matrix framework to investigate the interaction of extremely short optical pulses (ESPs) with transparent conducting oxides (TCOs). This approach captures not only electron populations, material polarization, and the permittivity, but also the quantum coherences between states. Compared to traditional momentum-space models, the energy-space formulation offers substantial computational simplification while retaining accuracy. Building on but going beyond the scope of Ref. [Un et al. (unpublished)], we focus on dynamical features previously unexplored. Our formulation reveals clear signatures of quantum coherence in the net absorption dynamics and highlights the emergence of strong excited-state absorption under intense excitation. Furthermore, we investigate the influence of pump pulse intensity on the local field's duration, spectral broadening, and shift, and phase induced by carrier dynamics, highlighting the absorptive nature of the nonlinear response. Our results provide a unified framework for understanding nonlinear light-matter interaction in dispersive, low-density electron systems driven far from equilibrium by intense broadband excitation.

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