Emergent metamagnetism and field-induced phase separation in the frustrated antiferromagnet
Phys. Rev. B 114, 034401 – Published 6 July, 2026
DOI: https://doi.org/10.1103/8wp3-3187
Abstract
A clear understanding of the physics of complex magnetic oxides is crucial for unlocking new pathways to design novel materials for technological applications. We present here a detailed investigation of the temperature- and magnetic-field-driven magnetic evolution of using a suite of complementary techniques, including neutron diffraction, Mössbauer spectroscopy, magnetization, and transverse susceptibility measurements. Below , the Fe sublattice orders into an incommensurate collinear spin-density-wave state with propagation vector . The exchange coupling drives a transition at to a commensurate noncollinear antiferromagnetic phase characterized by involving ordering of both and ions, followed by a further modification of the Er magnetic configuration below governed by dominant interactions. Strong geometrical frustration prevents complete long-range magnetic ordering, leaving a substantial fraction of spins in a short-range correlated state that serves as a metastable template for phase separation. Under an applied magnetic field of , the spins within these regions undergo a metamagnetic spin-flip transition, nucleating ferromagnetic clusters. This metamagnetic response remains fully reversible down to 8 K, while a crossover to an irreversible ferromagneticlike regime occurs at lower temperatures, attributed to kinetic arrest of the magnetic clusters. A complex field-induced phase separation is established, in which ferromagnetic clusters of distinct populations coexist with the long-range antiferromagnetic order of the Er sublattice. These findings underscore the complex interplay among magnetic anisotropy, magnetic frustration, and quenched disorder in stabilizing the magnetic ground state of .