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    Emergent metamagnetism and field-induced phase separation in the frustrated antiferromagnet BaErFeO4

    N. T. Dang1,2,*, T. P. Hoang1,2, V. Chlan3,†, T. Kmječ3, M. Rozprým3, M. Veverka3, J. Kohout3, L. V. Truong-Son4, T. L. Phan5 et al.

    G. S. Rymski6, D. L. Khoa7, N. T. M. Duc8,9,‡, D. P. Kozlenko10, S. E. Kichanov10, E. V. Lukin10, A. V. Rutkauskas10,§, and M. H. Phan8,9,∥

    • *Contact author: dangngoctoan1@duytan.edu.vn
    • †Contact author: chlan@mbox.troja.mff.cuni.cz
    • ‡Contact author: duc.ntm@vinuni.edu.vn
    • §Contact author: ranton@nf.jinr.ru
    • ∥Contact author: huong.pm@vinuni.edu.vn

    Phys. Rev. B 114, 034401 – Published 6 July, 2026

    DOI: https://doi.org/10.1103/8wp3-3187

    Abstract

    A clear understanding of the physics of complex magnetic oxides is crucial for unlocking new pathways to design novel materials for technological applications. We present here a detailed investigation of the temperature- and magnetic-field-driven magnetic evolution of BaErFeO4 using a suite of complementary techniques, including neutron diffraction, Mössbauer spectroscopy, dc magnetization, and transverse susceptibility measurements. Below TN1≈50K, the Fe sublattice orders into an incommensurate collinear spin-density-wave state with propagation vector k1=(0,0,∼0.4). The 3d−4f exchange coupling drives a transition at TN2≈32K to a commensurate noncollinear antiferromagnetic phase characterized by k2=(0.5,0,0.5) involving ordering of both Fe3+ and Er3+ ions, followed by a further modification of the Er magnetic configuration below TN3≈5K governed by dominant 4f−4f interactions. Strong geometrical frustration prevents complete long-range magnetic ordering, leaving a substantial fraction of spins in a short-range correlated state that serves as a metastable template for phase separation. Under an applied magnetic field of μ0H≈0.2T, the Er3+ spins within these regions undergo a metamagnetic spin-flip transition, nucleating ferromagnetic clusters. This metamagnetic response remains fully reversible down to 8 K, while a crossover to an irreversible ferromagneticlike regime occurs at lower temperatures, attributed to kinetic arrest of the magnetic clusters. A complex field-induced phase separation is established, in which ferromagnetic clusters of distinct populations coexist with the long-range antiferromagnetic order of the Er sublattice. These findings underscore the complex interplay among magnetic anisotropy, magnetic frustration, and quenched disorder in stabilizing the magnetic ground state of BaErFeO4.

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