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    Ultrafast carrier relaxation and coherent phonon dynamics in the kagome material CsTi3Bi5

    Liye Cao1,2, Fanbo Shen3, Zehao Yu1,2, Hongbo Hu1,2, Yanfeng Guo3,4, and Rongyan Chen1,2,*

    • 1Center for Advanced Quantum Studies and School of Physics and Astronomy, Beijing Normal University, Beijing 100875, China
    • 2Key Laboratory of Multiscale Spin Physics (Ministry of Education), Beijing Normal University, Beijing 100875, China
    • 3School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
    • 4ShanghaiTech Laboratory for Topological Physics, Shanghai 201210, China

    • *Contact author: rychen@bnu.edu.cn

    Phys. Rev. B 114, 285106 – Published 5 November, 2026

    DOI: https://doi.org/10.1103/8mgp-dwf2

    Abstract

    The kagome compound CsTi3Bi5 serves as a natural counterpart to the extensively studied CsV3Sb5, offering an ideal platform for directly comparing their emergent physical properties. Here, we employ ultrafast pump-probe spectroscopy to investigate the nonequilibrium carrier dynamics and collective excitations in CsTi3Bi5. The quasiparticle relaxation consists of several decay components, among which the fast subpicosecond decay is governed by the electron-phonon (e−ph) coupling. The extracted coupling constant of approximately 0.413±0.007 is smaller than that reported for CsV3Sb5. This weak-coupling strength may be one factor contributing to the absence of a charge-density-wave (CDW) order in CsTi3Bi5, even when its Van Hove singularities are tuned to the Fermi level, suggesting that e-ph coupling may play an important role in stabilizing the CDW state in CsV3Sb5. In addition, a coherent acoustic phonon mode with a frequency of 0.012 THz is identified, corresponding to a sound velocity of vs=1460 m/s. Combined with the absence of any observed coherent optical phonon modes, the anomalous hardening of this mode with increasing temperature further supports weak e-ph coupling. Together, these results advance the understanding of nonequilibrium carrier and lattice dynamics in kagome materials.

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