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    Weak electron correlations and itinerant 5f electrons in UFeGa5: A high-resolution ARPES and DFT study

    Xuwen He1,*, Xuebing Luo1,*, Bo Wang1,*, Wei Feng1, Dengpeng Yuan1, Yi Liu1, Yulu He1, Yaobo Huang2, Zhengtai Liu3 et al.

    Dawei Shen4, Mao Ye3, Jishan Liu3, Qin Liu1, Qunqing Hao1, Xiangfei Yang1, Yun Zhang1, S. Y. Tan1, Qiuyun Chen1,†, and Xinchun Lai1

    • *These authors contributed equally to this work.
    • †Contact author: sheqiuyun@126.com

    Phys. Rev. B 112, 205109 – Published 7 November, 2025

    DOI: https://doi.org/10.1103/8jss-xdxp

    Abstract

    Uranium compounds have long been of significant interest in condensed matter physics due to their diverse and often exotic properties, including heavy-fermion behavior, non-Fermi-liquid characteristics, quantum criticality, and unconventional superconductivity. These phenomena arise from the complex interplay between crystal structure, hybridization of localized 5f electrons with conduction electrons, and electron-electron correlations. Here, we present a comprehensive study of the electronic structure of UFeGa5, a layered uranium intermetallic compound, using high-resolution angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations. Three-dimensional electronic structure of UFeGa5 was systematically studied and fine structures of the U5f bands near the Fermi energy were clearly resolved. Our results reveal that UFeGa5 exhibits a predominantly itinerant nature of 5f electrons, with strong band dispersion and significant contributions to the Fermi surface. Theoretical calculations assuming itinerant 5f electrons are in excellent agreement with the experimental ARPES data, confirming the weak electron correlation effects in this compound. Temperature-dependent ARPES measurements further demonstrate that the f electrons retain itinerant across the studied temperature range (7.5 to 100 K).

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