Comparative Raman study of well-protected atomically thin and
Phys. Rev. B 112, 085408 – Published 6 August, 2025
DOI: https://doi.org/10.1103/7kzb-41xm
Abstract
Recently demonstrated intrinsic antiferromagnetic topological insulator has attracted wide attention, due to its elevated temperature for the observation of quantum phenomena, including quantum anomalous Hall effect and axion insulator states. However, the ongoing debate regarding layer-number determination and the surface layer degradation or reconstruction revealed by prior studies poses significant challenges for the in-depth exploration of the intrinsic properties of . Here, we present a systematic study of Raman spectroscopy in few-layer samples, which were freshly cleaved and protected in an inert atmosphere throughout the experiments, ensuring adequate sample protection. We establish one-to-one correspondence between layer number and low-frequency breathing modes based on the uncontaminated samples. Comparison of the Raman spectra between and , as well as between samples near and far from regions sectioned by focused ion beam (FIB), demonstrates that surface-layer degradation from to can be effectively prevented by avoiding air exposure and damage from the FIB. Our results provide a reliable reference for identifying the layer number and crystal structure. In this study, we provide a valuable benchmark for assessing the sample quality and pave the way for further realization on exotic topological phases of .