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    Raman fingerprint of the anisotropy transferability in the two-dimensional heterostructure ReS2/WSe2

    Yueying Cui1,2,*, Junming Song1,2,*, Ting Zheng1,*, Yuwei Xiong3,*, Junpeng Lu1, Weiwei Zhao1,2,†, Fang Yang2,‡, Hongwei Liu2,§, and Zhenhua Ni1,∥

    • 1School of Physics and Key Laboratory of MEMS of Ministry of Education, Southeast University, Nanjing 211189, China
    • 2School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, China
    • 3SEU-FEI Nano-Pico Center, Key Laboratory of MEMS of Ministry of Education, School of Integrated Circuits, Southeast University, Nanjing 210096, People's Republic of China

    • *These authors contributed equally to this work.
    • †Contact author: jianpiao1986@163.com
    • ‡Contact author: 06299@njnu.edu.cn
    • §Contact author: phylhw@njnu.edu.cn
    • ∥Contact author: zhni@seu.edu.cn

    Phys. Rev. B 112, 115429 – Published 23 September, 2025

    DOI: https://doi.org/10.1103/6ww2-m8w8

    Abstract

    Anisotropy-based two-dimensional heterostructures display distinct polarization traits, offering potential for detection and advanced applications. However, common studies often oversimplify anisotropy's properties to the use of anisotropic materials, leaving the true transmission of anisotropy in heterostructures as an unresolved question. Here, we demonstrate that the anisotropy is indeed transferred in the ReS2/WSe2 heterostructure via Raman scattering. The intrinsic anisotropy of the WSe2 in the as-fabricated heterostructure is clearly enhanced by the overlying ReS2 layer, while the anisotropy of monolayer ReS2 is partially erased. The changes in the Eg-like modes I and II in the ReS2 indicate that lattice engineering leads to the formation of regional distortions, potentially causing the weakening of anisotropy in polarized Raman spectroscopy. Furthermore, this anisotropy transferability can be applied to other semiconductor and layered materials. These findings provide insights into interlayer coupling and anisotropy modulation in van der Waals heterostructures, paving the way for future studies on symmetry engineering, anisotropic charge transport, and the design of functional materials with tailored directional properties.

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