Magnetic ground state, critical analysis of magnetization, and large magnetocaloric effect in ferromagnetically coupled kagome lattice
Phys. Rev. B 112, 104441 – Published 26 September, 2025
DOI: https://doi.org/10.1103/6sjq-dfj7
Abstract
We report a detailed study of the magnetic properties, critical analysis of magnetization, and magnetocaloric effect of a spin-2 kagome lattice . The experiments are complemented by the density functional band-structure calculations. The magnetic measurements suggest a highly frustrated nature of the compound due to competing ferro- and antiferromagnetic interactions, with the dominant one being ferromagnetic. It undergoes an unconventional ferromagnetic ordering at K and a field-induced metamagnetic transition in low fields, implying spin canting. A phase diagram is constructed that features three phase regimes. Indeed, the band-structure calculations reveal dominant ferromagnetic interaction along the chains that are coupled antiferromagnetically, yielding a frustrated kagome geometry. This compound shows a large magnetocaloric effect with isothermal entropy change J/kg-K, adiabatic temperature change K, and relative cooling power J/kg for a field change of 7 T. The critical analysis of magnetization and magnetocaloric parameters suggests that the transition is a second-order phase transition and it is a tricritical mean-field type. Owing to its large magnetocaloric parameters, second-order phase transition, and no thermal hysteresis, emerges as a potential rare-earth-free magnetic material for magnetic refrigeration.