Export citation

Export citation

Choose format for download:

Download Citation

    Magnetic correlations and crystal structure changes in Fe- and Ni-substituted ErCo2 with reversible giant magnetocaloric effect

    Simon Rosenqvist Larsen*, Noriki Terada†, Xin Tang, and Hiroaki Mamiya

    Yusuke Nambu

    Daisuke Okuyama

    Hossein Sepehri-Amin

    • *Contact author: larsen.simon@nims.go.jp
    • †Contact author: terada.noriki@nims.go.jp

    Phys. Rev. B 112, 014443 – Published 23 July, 2025

    DOI: https://doi.org/10.1103/6lt2-4pwb

    Abstract

    ErCo2 is a compound which has recently attracted attention as a potential magnetic refrigeration material for hydrogen liquefaction. The interest in the material is due to the large magnetocaloric effect it exhibits, the tunability of the transition temperature, and the recent discovery of the tunability of the order of the transition by small substitutions of transition metals [X. Tang et al., Nat. Commun. 13, 1817 (2022)]. The reason for the change in the order of the transition is not yet understood. In this study the microscopic magnetic correlations and crystal lattice distortions in ErCo2−xTx (T=Fe and Ni) are investigated using neutron and synchrotron x-ray diffraction, as well as AC susceptibility measurements. The results indicate that in contrast to the previous study, the cubic to rhombohedral structure change was not suppressed, although the way the unit cell expansion occurred did change. No significant changes were observed in the magnetic long-range order and crystal lattice symmetry, which still formed a ferrimagnetic and rhombohedral crystal structure below the phase transition temperature TC for all substitutions as well as pure ErCo2. However, an increase in magnetic short-range correlations above TC, which is strongly correlated with the entropy change and the dynamic AC susceptibility, was detected only in the substituted samples. Unlike pure ErCo2, the nucleation of the local ferrimagnetic clusters above TC occurs in the substituted samples, which significantly reduces the energy barrier between the higher-temperature cubic phase and the lower-temperature rhombohedral phase. We conclude that the reduction of the energy barrier due to the development of short-range order induced by chemical substitution at temperatures above TC is possibly the origin of the significant change in the nature of the phase transition in ErCo2.

    Physics Subject Headings (PhySH)

    Authorization Required

    We need you to provide your credentials before accessing this content.

    Supplemental Material (Subscription Required)

    References (Subscription Required)

    Outline

    Information

    Sign In to Your Journals Account

    Filter

    Filter

    Article Lookup

    Enter a citation