Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Nonthermal pairing glue of electrons in the steady state

Michele Pini1,2,*,†, Christian H. Johansen3,2,*, and Francesco Piazza1,2

  • *These authors contributed equally to this work.
  • †Contact author: michele.pini@uni-a.de

Phys. Rev. B 114, 074507 – Published 24 August, 2026

DOI: https://doi.org/10.1103/69b6-xzv7

Abstract

The study of mechanisms for enhancing superconductivity has been a central topic in condensed matter physics because of the combination of fundamental and technological interests. One promising route is to exploit nonequilibrium effects in the steady state. Efforts in this direction have so far focused on enhancing the pairing mechanism known from thermal equilibrium through modified distributions for the electrons or the bosons mediating the electron–electron interaction. In this work, we identify an additional pairing mechanism that is active only outside thermal equilibrium. By generalizing Eliashberg theory to nonequilibrium steady states using the Keldysh formalism, we derive a set of Eliashberg equations that capture the effect of this genuinely nonthermal pairing glue even in the weak-coupling regime. We discuss two examples where this mechanism has a major impact. First, in a temperature-bias setup, we find that superconductivity is enhanced when the boson mediator is colder than the electrons. Second, we find that an incoherent drive of the boson mediator at energies much greater than the temperature pushes the system far from thermal equilibrium but leaves the critical coupling essentially unchanged, owing to a competition between electron heating and the enhancement of pairing by the nonthermal glue.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (80)

  1. D. Fausti, R. I. Tobey, N. Dean, S. Kaiser, A. Dienst, M. C. Hoffmann, S. Pyon, T. Takayama, H. Takagi, and A. Cavalleri, Light-induced superconductivity in a stripe-ordered cuprate, Science 331, 189 (2011).
  2. D. Nicoletti, E. Casandruc, Y. Laplace, V. Khanna, C. R. Hunt, S. Kaiser, S. S. Dhesi, G. D. Gu, J. P. Hill, and A. Cavalleri, Optically induced superconductivity in striped La2−xBaxCuO4 by polarization-selective excitation in the near infrared, Phys. Rev. B 90, 100503(R) (2014).
  3. W. Hu, S. Kaiser, D. Nicoletti, C. R. Hunt, I. Gierz, M. C. Hoffmann, M. Le Tacon, T. Loew, B. Keimer, and A. Cavalleri, Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling, Nat. Mater. 13, 705 (2014).
  4. M. Mitrano, A. Cantaluppi, D. Nicoletti, S. Kaiser, A. Perucchi, S. Lupi, P. Di Pietro, D. Pontiroli, M. Riccò, S. R. Clark, D. Jaksch, and A. Cavalleri, Possible light-induced superconductivity in K3C60 at high temperature, Nature (London) 530, 461 (2016).
  5. A. Cantaluppi, M. Buzzi, G. Jotzu, D. Nicoletti, M. Mitrano, D. Pontiroli, M. Riccò, A. Perucchi, P. Di Pietro, and A. Cavalleri, Pressure tuning of light-induced superconductivity in K3C60, Nat. Phys. 14, 837 (2018).
  6. M. Budden, T. Gebert, M. Buzzi, G. Jotzu, E. Wang, T. Matsuyama, G. Meier, Y. Laplace, D. Pontiroli, M. Riccò, F. Schlawin, D. Jaksch, and A. Cavalleri, Evidence for metastable photo-induced superconductivity in K3C60, Nat. Phys. 17, 611 (2021).
  7. K. Isoyama, N. Yoshikawa, K. Katsumi, J. Wong, N. Shikama, Y. Sakishita, F. Nabeshima, A. Maeda, and R. Shimano, Light-induced enhancement of superconductivity in iron-based superconductor FeSe0.5Te0.5, Commun. Phys. 4, 160 (2021).
  8. E. Rowe, B. Yuan, M. Buzzi, G. Jotzu, Y. Zhu, M. Fechner, M. Först, B. Liu, D. Pontiroli, M. Riccò, and A. Cavalleri, Resonant enhancement of photo-induced superconductivity in K3C60, Nat. Phys. 19, 1821 (2023).
  9. F. J. Garcia-Vidal, C. Ciuti, and T. W. Ebbesen, Manipulating matter by strong coupling to vacuum fields, Science 373, eabd0336 (2021).
  10. F. Schlawin, D. M. Kennes, and M. A. Sentef, Cavity quantum materials, Appl. Phys. Rev. 9, 011312 (2022).
  11. J. Bloch, A. Cavalleri, V. Galitski, M. Hafezi, and A. Rubio, Strongly correlated electron–photon systems, Nature (London) 606, 41 (2022).
  12. A. Thomas, E. Devaux, K. Nagarajan, T. Chervy, M. Seidel, D. Hagenmüller, S. Schütz, J. Schachenmayer, C. Genet, G. Pupillo, and T. W. Ebbesen, Exploring superconductivity under strong coupling with the vacuum electromagnetic field, J. Chem. Phys. 162, 134701 (2025).
  13. I. Keren, T. A. Webb, S. Zhang, J. Xu, D. Sun, B. S. Y. Kim, D. Shin, S. S. Zhang, J. Zhang, G. Pereira, et al., Cavity-altered superconductivity, arXiv:2505.17378.
  14. G. M. Eliashberg, Film superconductivity stimulated by a high-frequency field, Zh. Eksp.Teor. Fiz. Pis. Red. 11, 186 (1970) [JETP Lett. 11, 114 (1970)].
  15. B. I. Ivlev, S. G. Lisitsyn, and G. M. Eliashberg, Nonequilibrium excitations in superconductors in high-frequency fields, J. Low Temp. Phys. 10, 449 (1973).
  16. A. F. G. Wyatt, V. M. Dmitriev, W. S. Moore, and F. W. Sheard, Microwave-enhanced critical supercurrents in constricted tin films, Phys. Rev. Lett. 16, 1166 (1966).
  17. A. H. Dayem and J. J. Wiegand, Behavior of thin-film superconducting bridges in a microwave field, Phys. Rev. 155, 419 (1967).
  18. T. M. Klapwijk, J. N. van den Bergh, and J. E. Mooij, Radiation-stimulated superconductivity, J. Low Temp. Phys. 26, 385 (1977).
  19. J. B. Curtis, Z. M. Raines, A. A. Allocca, M. Hafezi, and V. M. Galitski, Cavity quantum Eliashberg enhancement of superconductivity, Phys. Rev. Lett. 122, 167002 (2019).
  20. M. M. Islam, M. Pini, R. Flores-Calderón, and F. Piazza, Cavity-induced Eliashberg effect: Superconductivity vs charge density wave, arXiv:2509.07865.
  21. F. Schlawin, A. Cavalleri, and D. Jaksch, Cavity-mediated electron-photon superconductivity, Phys. Rev. Lett. 122, 133602 (2019).
  22. H. Gao, F. Schlawin, M. Buzzi, A. Cavalleri, and D. Jaksch, Photoinduced electron pairing in a driven cavity, Phys. Rev. Lett. 125, 053602 (2020).
  23. A. Chakraborty and F. Piazza, Long-range photon fluctuations enhance photon-mediated electron pairing and superconductivity, Phys. Rev. Lett. 127, 177002 (2021).
  24. G. M. Andolina, A. De Pasquale, F. M. D. Pellegrino, I. Torre, F. H. L. Koppens, and M. Polini, Amperean superconductivity cannot be induced by deep subwavelength cavities in a two-dimensional material, Phys. Rev. B 109, 104513 (2024).
  25. A. Chakraborty, M. Pini, M. Zündel, and F. Piazza, Controlling collective phenomena via the quantum state of interaction mediators: Changing the criticality of photon-mediated superconductivity via Fock states of light, PRX Quantum 6, 020341 (2025).
  26. M. A. Sentef, M. Ruggenthaler, and A. Rubio, Cavity quantum-electrodynamical polaritonically enhanced electron-phonon coupling and its influence on superconductivity, Sci. Adv. 4, eaau6969 (2018).
  27. I.-T. Lu, D. Shin, M. K. Svendsen, H. Hübener, U. De Giovannini, S. Latini, M. Ruggenthaler, and A. Rubio, Cavity-enhanced superconductivity in MgB2 from first-principles quantum electrodynamics (QEDFT), Proc. Natl. Acad. Sci. USA 121, e2415061121 (2024).
  28. C. J. Eckhardt, S. Chattopadhyay, D. M. Kennes, E. A. Demler, M. A. Sentef, and M. H. Michael, Theory of resonantly enhanced photo-induced superconductivity, Nat. Commun. 15, 2300 (2024).
  29. V. K. Kozin, E. Thingstad, D. Loss, and J. Klinovaja, Cavity-enhanced superconductivity via band engineering, Phys. Rev. B 111, 035410 (2025).
  30. G. Eliashberg, Interactions between electrons and lattice vibrations in a superconductor, Sov. Phys. JETP 11, 696 (1960).
  31. G. Eliashberg, Temperature Green's function for electrons in a superconductor, Sov. Phys. JETP 12, 1000 (1961).
  32. F. Marsiglio, Eliashberg theory: A short review, Ann. Phys. 417, 168102 (2020).
  33. A. V. Chubukov, A. Abanov, I. Esterlis, and S. A. Kivelson, Eliashberg theory of phonon-mediated superconductivity—when it is valid and how it breaks down, Ann. Phys. 417, 168190 (2020).
  34. F. Marsiglio and J. P. Carbotte, Gap function and density of states in the strong-coupling limit for an electron-boson system, Phys. Rev. B 43, 5355 (1991).
  35. R. Combescot, Strong-coupling limit of Eliashberg theory, Phys. Rev. B 51, 11625 (1995).
  36. Y. Wang and A. Chubukov, Quantum-critical pairing in electron-doped cuprates, Phys. Rev. B 88, 024516 (2013).
  37. F. Marsiglio, Eliashberg theory in the weak-coupling limit, Phys. Rev. B 98, 024523 (2018).
  38. S. Mirabi, R. Boyack, and F. Marsiglio, Eliashberg theory in the weak-coupling limit: Results on the real frequency axis, Phys. Rev. B 101, 064506 (2020).
  39. L. M. Sieberer, M. Buchhold, and S. Diehl, Keldysh field theory for driven open quantum systems, Rep. Prog. Phys. 79, 096001 (2016).
  40. A. Kamenev, Field Theory of Non-Equilibrium Systems (Cambridge University Press, Cambridge, 2011).
  41. A. F. Kemper, M. A. Sentef, B. Moritz, J. K. Freericks, and T. P. Devereaux, Direct observation of Higgs mode oscillations in the pump-probe photoemission spectra of electron-phonon mediated superconductors, Phys. Rev. B 92, 224517 (2015).
  42. M. A. Sentef, A. F. Kemper, A. Georges, and C. Kollath, Theory of light-enhanced phonon-mediated superconductivity, Phys. Rev. B 93, 144506 (2016).
  43. L. Grunwald, G. Passetti, and D. M. Kennes, Dynamical onset of light-induced unconventional superconductivity—A Yukawa-Sachdev-Ye-Kitaev study, Commun. Phys. 7, 79 (2024).
  44. Y. Murakami, N. Tsuji, M. Eckstein, and P. Werner, Nonequilibrium steady states and transient dynamics of conventional superconductors under phonon driving, Phys. Rev. B 96, 045125 (2017).
  45. M. Babadi, M. Knap, I. Martin, G. Refael, and E. Demler, Theory of parametrically amplified electron-phonon superconductivity, Phys. Rev. B 96, 014512 (2017).
  46. L. Rademaker, Y. Wang, T. Berlijn, and S. Johnston, Enhanced superconductivity due to forward scattering in FeSe thin films on SrTiO3 substrates, New J. Phys. 18, 022001 (2016).
  47. Y. Wang, K. Nakatsukasa, L. Rademaker, T. Berlijn, and S. Johnston, Aspects of electron–phonon interactions with strong forward scattering in FeSe thin films on SrTiO3 substrates, Supercond. Sci. Technol. 29, 054009 (2016).
  48. G. Varelogiannis, A. Perali, E. Cappelluti, and L. Pietronero, Density-of-states-driven anisotropies induced by momentum decoupling in Bi2Sr2CaCu2O8, Phys. Rev. B 54, R6877 (1996).
  49. O. Danylenko, O. Dolgov, M. Kulic, and V. Oudovenko, Normal and superconducting state in the presence of forward electron-phonon and impurity scattering, Eur. Phys. J. B 9, 201 (1999).
  50. K. Yang and S. L. Sondhi, Low-energy collective modes, Ginzburg-Landau theory, and pseudogap behavior in superconductors with long-range pairing interactions, Phys. Rev. B 62, 11778 (2000).
  51. R. Flores-Calderón, M. M. Islam, M. Pini, and F. Piazza, Nonthermal electron-photon steady states in open cavity quantum materials, Phys. Rev. Res. 7, 013073 (2025).
  52. R. Combescot, Critical temperature of superconductors: Exact solution from Eliashberg equations on the weak-coupling side, Phys. Rev. B 42, 7810 (1990).
  53. G. Jarc, S. Y. Mathengattil, A. Montanaro, F. Giusti, E. M. Rigoni, R. Sergo, F. Fassioli, S. Winnerl, S. Dal Zilio, D. Mihailovic, et al., Cavity-mediated thermal control of metal-to-insulator transition in 1T-TaS2, Nature (London) 622, 487 (2023).
  54. B. D. Faeth, S.-L. Yang, J. K. Kawasaki, J. N. Nelson, P. Mishra, C. T. Parzyck, C. Li, D. G. Schlom, and K. M. Shen, Incoherent Cooper pairing and pseudogap behavior in single-layer FeSe/SrTiO3, Phys. Rev. X 11, 021054 (2021).
  55. A. Altland and B. D. Simons, Condensed Matter Field Theory (Cambridge University Press, Cambridge, 2010).
  56. The conjugation relation between anomalous retarded (ΔωR) and advanced (ΔωA) self-energies is true only at |k|=kF and for the gauge choice Δω=0R∈R. This is discussed in detail in Appendix pp3.
  57. Note that in principle the spectral gap should be self-consistently evaluated at the gap edge via the equation Δ0=ReΔω=Δ0R [38], but Δ0≪ω0,κ in weak-coupling regime, so that Δ0=Δω≈0R is a good approximation.
  58. We use a linear coupling to a fermionic bath to describe this process. Such a simplified description avoids the additional complexity of a bosonic bath, and since we are anyway focusing on a weakly-coupled cryostat the precise modeling details have minimal impact on the observed physics.
  59. We remark that the small discrepancy of the weak-coupling solution at larger T0 comes mostly from the weak-coupling approximation of the thermal contribution gc,th of Eq.  (2), rather than from the nonthermal contribution in Eq.  (1). This is also discussed at the end of Sec. 6b.
  60. More refined weak-coupling treatments at thermal equilibrium have been developed by accounting for the frequency dependence of ΔωR arising from the bosonic propagator (cf. Fig.  7) in Eq.  (25) [37, 38, 46].
  61. C. H. Johansen and M. Pini, Zenodo repository for “non-thermal pairing glue of electrons in the steady state”, Zenodo, 2025, doi: 10.5281/zenodo.18017897.
  62. The scaling constant is chosen to have a particularly simple form of the propagator, as shown in Eq.  (F30).
  63. Note that the initial distribution of the electrons will actually never enter the steady-state results, since the memory of it will be lost because of the interaction with the cryostat and/or the bosons.
  64. M. Protter, R. Boyack, and F. Marsiglio, Functional-integral approach to Gaussian fluctuations in Eliashberg theory, Phys. Rev. B 104, 014513 (2021).
  65. The symmetry of the real boson forces DtR to be real and DtK to be imaginary.
  66. A. Dalal, J. Ruhman, and V. Kozii, Field theory of a superconductor with repulsion, Phys. Rev. B 108, 214521 (2023).
  67. R. A. Horn and C. R. Johnson, Matrix Analysis, 2nd ed. (Cambridge University Press, Cambridge, 2013).
  68. These distributions correspond to the thermal Bose-Einstein nωb=(Fωb−1)/2=(eω/T−1)−1 and Fermi-Dirac nωe=(1−Fωe)/2=(eω/T+1)−1 occupations for bosons and electrons, respectively.
  69. A. L. Fetter and J. D. Walecka, Quantum Theory of Many-Particle Systems (McGraw-Hill, Boston, 1971).
  70. The factor of 2 in Eqs. (B14) and (B15) comes from a different definition of the free boson Hamiltonian in Eq.  (10) with respect to Ref. [64].
  71. F. Marsiglio, M. Schossmann, and J. P. Carbotte, Iterative analytic continuation of the electron self-energy to the real axis, Phys. Rev. B 37, 4965 (1988).
  72. D. J. Thouless, Perturbation theory in statistical mechanics and the theory of superconductivity, Ann. Phys. 10, 553 (1960).
  73. W. L. McMillan, Transition temperature of strong-coupled superconductors, Phys. Rev. 167, 331 (1968).
  74. We remark that, at thermal equilibrium, McMillian's algorithm [73] is not the best method to obtain the real-frequency order parameter ΔωR/Δω=0R at the phase transition. A more advanced method, which first exploits the numerical advantage of the Matsubara frequency axis and then analytically continues the result to the real axis with a numerically exact procedure, has been developed by Marsiglio and Carbotte [34, 38, 71]. The latter method, however, cannot be applied to our nonthermal case as it still relies on Matsubara frequencies.
  75. L. G. Ferreira, Theory and method for accelerating the convergence of self-consistent electronic structure calculations, J. Comput. Phys. 36, 198 (1980).
  76. M. Pini, P. Pieri, and G. C. Strinati, Fermi gas throughout the BCS-BEC crossover: Comparative study of t-matrix approaches with various degrees of self-consistency, Phys. Rev. B 99, 094502 (2019).
  77. C. H. Johansen, B. Frank, and J. Lang, Spectral functions of the strongly interacting three-dimensional Fermi gas, Phys. Rev. A 109, 023324 (2024).
  78. We note that a similar approximation for ΔωR is also found at zeroth order in the weak-coupling limit of standard Eliashberg theory at thermal equilibrium, see Ref. [38].
  79. N. Kopnin, Theory of Nonequilibrium Superconductivity (Oxford University Press, Oxford, 2001).
  80. P. B. Allen and B. Mitrović, Theory of Superconducting Tc, Solid State Physics (Academic Press, New York, 1983), Vol. 37, pp. 1–92.

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation