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    Interplay of magnetism and correlated electron behavior in the kagome metal TbNb6Sn6

    Rukshana Pervin1,2, Deng Hu1,2, Mir Basit Hussain3, Chao Xiong1,2, Liu Yang1,2, Peng Zhu1,2, Caizhen Li1,2,*, and Zhiwei Wang1,2,4,†

    • *Contact author: licaizhen@bit.edu.cn
    • †Contact author: zhiweiwang@bit.edu.cn

    Phys. Rev. B 113, 075101 – Published 2 February, 2026

    DOI: https://doi.org/10.1103/5x1m-9st7

    Abstract

    Kagome-based magnetic metals are recognized as exemplary systems for the study of quantum materials, offering a distinctive framework to investigate the interrelation of topologically nontrivial electronic structures, geometrically frustrated magnetic moments (f≈7), and strongly correlated electron phenomena. The growth and detailed analysis of the 4d kagome metal TbNb6Sn6 are reported, in which a kagome network of Nb atoms is integrated with a triangularly frustrated arrangement of localized Tb3+ moments. High-quality crystals are found to adopt the centrosymmetric HfFe6Ge6-type structure (P6/mmm), with lattice constants precisely refined to a=b=5.75791Å and c=9.55520Å. Striking uniaxial anisotropy is revealed by magnetization measurements, with the magnetic susceptibility along the c direction exceeding the in-plane susceptibility by nearly 50-fold just above 3 K, indicating a strong out-of-plane alignment preference of the Tb3+ 4f moments. Two successive magnetic transitions are observed at zero magnetic field at TN=2.91 K and T2=2.32 K. When a magnetic field is applied along the c direction, four distinct metamagnetic transitions are observed at low temperatures, culminating in a fully polarized moment of 8.24 μB/Tb ion at 2 K above 3.6 T, as evidenced by both magnetization and resistivity measurements. A positive, nonsaturating magnetoresistance and a nonlinear Hall effect are exhibited by the compound across the full temperature range studied. First-principles calculations show that the Fermi level is dominated by Nb 4d orbitals, which generate kagome-derived bands featuring Dirac crossings and Van Hove singularities indicative of nontrivial topology. The potential of the RNb6Sn6 family as a versatile platform for realizing emergent quantum states is highlighted by the combination of tunable magnetic anisotropy, complex spin textures, and multiband conduction.

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