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    Intertwined charge and spin density waves in trilayer nickelate La4Ni3O10 revealed by La139 NQR

    Jie Dou1,2,*, Feiyu Li3,*, Mingxin Zhang4,*, Jun Luo1, Shuo Li1, Aifang Fang5,6, Jie Yang1, Yanpeng Qi4,7,8,†, Junjie Zhang3,‡ et al.

    Rui Zhou1,2,§

    • *These authors contributed equally to this work.
    • †Contact author: qiyp@shanghaitech.edu.cn
    • ‡Contact author: junjie@sdu.edu.cn
    • §Contact author: rzhou@iphy.ac.cn

    Phys. Rev. B 113, 054522 – Published 24 February, 2026

    DOI: https://doi.org/10.1103/5n3k-gtn9

    Abstract

    The discovery of superconducting transitions in pressurized La3Ni2O7 and La4Ni3O10 has highlighted the pivotal role of density wave (DW) orders in nickelate superconductors. To gain a comprehensive understanding of the superconducting state, it is essential to elucidate the nature of the DW order. In this study, we utilized La139 nuclear quadrupole resonance (NQR) to investigate the charge-density wave (CDW) and spin-density wave (SDW) orders in both single-crystal and polycrystalline La4Ni3O10. Near TDW≈133K, an abrupt change in both the linewidth and frequency of the La(2) site in the single-crystal sample provides compelling evidence for a first-order-like phase transition. The pronounced broadening of the NQR lines indicates the incommensurate nature of the DW order. Furthermore, the spin-lattice relaxation rate divided by temperature 1/T1T exhibits a strong enhancement at TDW, indicating the strong spin fluctuations above the first-order DW transition. These observations suggest an intricate interplay between incommensurate CDW and SDW orders. Our findings offer critical insights into the microscopic mechanisms of the DW state in La4Ni3O10 and establish an essential framework for exploring the interplay between DW and superconducting phases in nickelate superconductors.

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