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    Plasmon-enhanced quadrupole transitions of Rydberg excitons in Cu2O

    David Ziemkiewicz* and Sylwia Zielińska-Raczyńska

    • *Contact author: david.ziemkiewicz@utp.edu.pl

    Phys. Rev. B 112, 195306 – Published 19 November, 2025

    DOI: https://doi.org/10.1103/5gt4-ghhf

    Abstract

    A mechanism for amplification of weak quadrupole transitions of Rydberg excitons in Cu2O by a plasmonic nanostructure is investigated. The theoretical description of exciton-plasmon interaction is presented and a field averaging approximation is proposed for calculations involving large excitons. Various types of copper, silver and gold-based plasmonic nanostructures are considered and their potential for enhancing quadrupole transitions is evaluated. The change of eigenstates and eigenenergies as the exciton approaches the semiconductor-metal interface is also analyzed.

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