- Letter
- Open Access
Light-induced spin-polarized desorption of Rb atoms from Co surfaces
Phys. Rev. B 114, L111412 – Published 24 August, 2026
DOI: https://doi.org/10.1103/56hb-jcdl
Abstract
We investigated the spin polarization of Rb atoms undergoing light-induced desorption from a spin-polarized Co (110) surface. Desorption of Rb atoms was induced via pulsed UV irradiation of the Rb-adsorbed Co surface. The number of desorbed atoms, their velocity distribution, and their spin polarization were measured via the absorption of circularly polarized light resonant with the desorbed Rb atoms. The results were analyzed in conjunction with density functional theory calculations, indicating that the desorbed Rb atoms were spin polarized. This was explained by a nonthermal desorption mechanism accompanying spin-polarized electron transfer between the Co surface and adsorbed Rb.
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References (27)
- M. Landolt and M. Campagna, Demagnetization of the Ni(100) surface by hydrogen adsorption, Phys. Rev. Lett. 39, 568 (1977).
- A. Cao, V. J. Bukas, V. Shadravan, Z. Wang, H. Li, J. Kibsgaard, I. Chorkendorff, and J. K. Nørskov, A spin promotion effect in catalytic ammonia synthesis, Nat. Commun. 13, 2382 (2022).
- A. Cao and J. K. Nørskov, Spin effects in chemisorption and catalysis, ACS Catal. 13, 3456 (2023).
- K. Asakawa, Y. Miura, N. Nagatsuka, K. Takeyasu, M. Matsumoto, and K. Fukutani, Electronic and spin structure of O- and H-adsorbed surfaces, Phys. Rev. B 99, 085442 (2019).
- M. Kurahashi, X. Sun, and Y. Yamauchi, Recovery of the half-metallicity of an surface by atomic hydrogen adsorption, Phys. Rev. B 81, 193402 (2010).
- G. S. Parkinson, N. Mulakaluri, Y. Losovyj, P. Jacobson, R. Pentcheva, and U. Diebold, Semiconductor–half metal transition at the surface upon hydrogen adsorption, Phys. Rev. B 82, 125413 (2010).
- X. Ren, T. Wu, Y. Sun, Y. Li, G. Xian, X. Liu, C. Shen, J. Gracia, H.-J. Gao, H. Yang, et al., Spin-polarized oxygen evolution reaction under magnetic field, Nat. Commun. 12, 2608 (2021).
- Z. Fang, W. Zhao, T. Shen, D. Qiu, Y. Lv, X. Hou, and Y. Hou, Spin-modulated oxygen electrocatalysis, Precis. Chem. 1, 395 (2023).
- A. Ikeda, M. Matsumoto, S. Ogura, K. Fukutani, and T. Okano, Photostimulated desorption of Xe from Au(001) surfaces via transient formation, Phys. Rev. B 84, 155412 (2011).
- K. Asakawa, N. Tanabe, T. Kawauchi, K. Fukutani, and A. Hatakeyama, Optical and spin-selective time-of-flight measurement of light-induced desorption of Rb from surfaces, Sci. Rep. 13, 14965 (2023).
- K. Zhang, A. Cao, L. H. Wandall, J. Vernieres, J. Kibsgaard, J. K. Nørskov, and I. Chorkendorff, Spin-mediated promotion of Co catalysts for ammonia synthesis, Science 383, 1357 (2024).
- K. Asakawa, Y. Tanaka, K. Uemura, N. Matsuzaka, K. Nishikawa, Y. Oguma, H. Usui, and A. Hatakeyama, Measurement of the temperature dependence of dwell time and spin relaxation probability of Rb atoms on paraffin surfaces using a beam-scattering method, Phys. Rev. A 104, 063106 (2021).
- Y. Nukaga, M. Ohtake, M. Futamoto, F. Kirino, N. Fujita, and N. Inaba, Structure and magnetic properties of Co epitaxial thin films grown on MgO single-crystal substrates, IEEE Trans. Magn. 45, 2519 (2009).
- G. Kresse and J. Hafner, Ab initio molecular dynamics for liquid metals, Phys. Rev. B 47, 558 (1993).
- G. Kresse and D. Joubert, From ultrasoft pseudopotentials to the projector augmented-wave method, Phys. Rev. B 59, 1758 (1999).
- B. Hammer, L. B. Hansen, and J. K. Nørskov, Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals, Phys. Rev. B 59, 7413 (1999).
- P. E. Blöchl, Projector augmented-wave method, Phys. Rev. B 50, 17953 (1994).
- H. J. Monkhorst and J. D. Pack, Special points for Brillouin-zone integrations, Phys. Rev. B 13, 5188 (1976).
- S. Grimme, J. Antony, S. Ehrlich, and H. Krieg, A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu, J. Chem. Phys. 132, 154104 (2010).
- J.-X. Liu, H.-Y. Su, D.-P. Sun, B.-Y. Zhang, and W.-X. Li, Crystallographic dependence of CO activation on cobalt catalysts: Hcp versus fcc, J. Am. Chem. Soc. 135, 16284 (2013).
- M. Wilde, I. Beauport, F. Stuhl, K. Al-Shamery, and H.-J. Freund, Adsorption of potassium on at ionic and metallic coverages and UV-laser-induced desorption, Phys. Rev. B 59, 13401 (1999).
- D. Budker, W. Gawlik, D. F. Kimball, S. M. Rochester, V. V. Yashchuk, and A. Weis, Resonant nonlinear magneto-optical effects in atoms, Rev. Mod. Phys. 74, 1153 (2002).
- F. M. Zimmermann and W. Ho, Velocity distributions of photochemically desorbed molecules, J. Chem. Phys. 100, 7700 (1994).
- K. Momma and F. Izumi, VESTA3 for three-dimensional visualization of crystal, volumetric and morphology data, J. Appl. Cryst. 44, 1272 (2011).
- D. S. D. Gunn and S. J. Jenkins, Adsorbate modification of the structural, electronic, and magnetic properties of ferromagnetic fcc surfaces, Phys. Rev. B 83, 115403 (2011).
- E. Hirose and E. Torikai, Spin dependent scattering of Cs atoms from ferromagnetic surfaces, J. Magn. Magn. Mater. 310, 2740 (2007).
- K. Asakawa, Replication Data for: Light-induced spin-polarized desorption of Rb atoms from Co surfaces, Harvard Dataverse, V1, 2025, https://doi.org/10.7910/DVN/NDTKIH.