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    Nonadiabatic phonon renormalization in metallic versus insulating rutile oxides

    Reshma Kumawat, Shubham Farswan, Simranjeet Kaur, and Kaushik Sen*

    • *Contact author: kaushik.sen@physics.iitd.ac.in

    Phys. Rev. B 113, 214320 – Published 22 June, 2026

    DOI: https://doi.org/10.1103/4nhr-dvbn

    Abstract

    We present a comparative Raman scattering study of metallic rutile oxides (RuO2 and IrO2) and insulating rutiles (TiO2 and SnO2). Temperature-dependent Raman spectra reveal that metallic compounds exhibit pronounced phonon frequency hardening [ω(11K)−ω(300K)=Δω≈6−10cm−1], whereas the insulating rutiles show only modest hardening Δω≈1−3cm−1. In contrast, the linewidth changes ΔΓ≈1–7cm−1 do not display a systematic metallic-insulating classification. Fits with the conventional Klemens anharmonic decay model reproduce the overall temperature trends but yield inconsistent anharmonic parameters for the metallic compounds when benchmarked against insulating rutile analogs. A modified Klemens framework, incorporating an additional T2 correction to the phonon frequency arising from the electronic contribution to the phonon self-energy, quantitatively accounts for the enhanced renormalization observed in metallic systems. These results establish finite nonadiabatic electron-phonon coupling in metallic rutiles and demonstrate that phonon renormalization can be identified even in the absence of observable Fano asymmetry in the phonon line shapes.

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