Nonadiabatic phonon renormalization in metallic versus insulating rutile oxides
Phys. Rev. B 113, 214320 – Published 22 June, 2026
DOI: https://doi.org/10.1103/4nhr-dvbn
Abstract
We present a comparative Raman scattering study of metallic rutile oxides ( and ) and insulating rutiles ( and ). Temperature-dependent Raman spectra reveal that metallic compounds exhibit pronounced phonon frequency hardening , whereas the insulating rutiles show only modest hardening . In contrast, the linewidth changes do not display a systematic metallic-insulating classification. Fits with the conventional Klemens anharmonic decay model reproduce the overall temperature trends but yield inconsistent anharmonic parameters for the metallic compounds when benchmarked against insulating rutile analogs. A modified Klemens framework, incorporating an additional correction to the phonon frequency arising from the electronic contribution to the phonon self-energy, quantitatively accounts for the enhanced renormalization observed in metallic systems. These results establish finite nonadiabatic electron-phonon coupling in metallic rutiles and demonstrate that phonon renormalization can be identified even in the absence of observable Fano asymmetry in the phonon line shapes.