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    Deciphering the absence of charge density waves in the V-based kagome metal CsV6Sb6

    Rongxiao Du1,*, Yunfan Yang1,*, Wenxin Lv2,3, Junhong Yu1,†, Hang Zhang1,‡, Hechang Lei2,3,§, and Jianbo Hu1,4,∥

    • *These authors contributed equally to this work.
    • †Contact author: jyu012@e.ntu.edu.sg
    • ‡Contact author: zhanghang@caep.cn
    • §Contact author: hlei@ruc.edu.cn
    • ∥Contact author: jianbo.hu@caep.cn

    Phys. Rev. B 113, 245119 – Published 9 June, 2026

    DOI: https://doi.org/10.1103/3vlt-zz94

    Abstract

    While charge density waves (CDWs) are a hallmark of the kagome metal CsV3Sb5, their absence in the bilayer counterpart CsV6Sb6 remains a notable exception, with the underlying mechanism yet to be elucidated. Here, integrating ultrafast spectroscopy with first-principles calculations, we demonstrate that the lack of charge orderings in CsV6Sb6 originates from a synergy between an altered electronic structure and fundamentally weakened electron-lattice coupling. Experimentally, coherent phonon dynamics exhibit purely conventional anharmonic behavior without CDW-associated anomalies, while electron dynamics reveal a markedly reduced electron-phonon coupling strength (i.e., 0.13 in CsV6Sb6 versus 0.88 in CsV3Sb5). Consistent with these experimental observations, first-principles calculations indicate an absence of Fermi-surface nesting and a shift of Van Hove singularities away from the Fermi level in CsV6Sb6. Together, our results establish a unified physical picture in which suppressed electronic instabilities and weak lattice coupling preclude CDW formation in bilayer kagome metals.

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