Deciphering the absence of charge density waves in the V-based kagome metal
Phys. Rev. B 113, 245119 – Published 9 June, 2026
DOI: https://doi.org/10.1103/3vlt-zz94
Abstract
While charge density waves (CDWs) are a hallmark of the kagome metal , their absence in the bilayer counterpart remains a notable exception, with the underlying mechanism yet to be elucidated. Here, integrating ultrafast spectroscopy with first-principles calculations, we demonstrate that the lack of charge orderings in originates from a synergy between an altered electronic structure and fundamentally weakened electron-lattice coupling. Experimentally, coherent phonon dynamics exhibit purely conventional anharmonic behavior without CDW-associated anomalies, while electron dynamics reveal a markedly reduced electron-phonon coupling strength (i.e., 0.13 in versus 0.88 in ). Consistent with these experimental observations, first-principles calculations indicate an absence of Fermi-surface nesting and a shift of Van Hove singularities away from the Fermi level in . Together, our results establish a unified physical picture in which suppressed electronic instabilities and weak lattice coupling preclude CDW formation in bilayer kagome metals.