B-site disorder induced cluster glass and magnetoresistance behaviors in double perovskite
Phys. Rev. B 114, 194419 – Published 22 October, 2026
DOI: https://doi.org/10.1103/35wk-wmyj
Abstract
In this work, magnetic and transport properties of are studied in detail. The absence of a superlattice peak at in the x-ray diffraction pattern indicates the Mn/Ru disorder at B-site, known as B-site disorder. The ZFC curve exhibits a weak ferromagnetic transition around , followed by a cluster glass transition at , as validated by frequency-dependent ac susceptibility studies. The high-temperature Curie-Weiss fit reveals predominant ferromagnetic interactions, while the S-shape of the M–H hysteresis loop at 300 K indicates the presence of short-range ferromagnetic correlations above . Resistivity follows the small polaron hopping (SPH) model in the 118–380 K temperature range, yielding a room-temperature conductivity of 3.02 S/cm, which suggests semiconducting-like behavior at room temperature. Temperature-dependent magnetoresistance (MR) displays anomalies at ∼230 K and ∼30 K corresponding to the high-temperature ferromagnetic transition and low-temperature cluster glass transition , respectively. Field-dependent MR shows a sharp increase at low fields below the cluster glass temperature, suggesting spin-polarized intercluster tunnelling of charge carriers. The gradual linear increase in MR with the applied magnetic field at high temperature is attributed to the intrinsic suppression of spin-disorder scattering induced by the B-site disorder. The absence of signature corresponding to in the vs T curve further supports cluster glass behavior.