Magnetism and correlated electrons in
Phys. Rev. B 112, 235164 – Published 23 December, 2025
DOI: https://doi.org/10.1103/2twh-qbdn
Abstract
We report the synthesis, structure, and physical properties of a new quaternary nitride . The compound crystallizes in the -type structure (/mmm), featuring distinctive square sheets within block layers. Physical characterizations reveal enhanced electron correlations evidenced by a Sommerfeld coefficient substantially larger than band calculations and pressure-induced deviation from Fermi-liquid behavior. Magnetic measurements show short-range antiferromagnetic correlations developing around 460 K, followed by long-range magnetic ordering at 14 K. Additionally, subtle anomalies at 378 K suggest possible electronic ordering. First-principles calculations reveal nearly flat Cr- bands near the Fermi level and predict a striped antiferromagnetic ground state. This work demonstrates how electron count variation in the -type structure family leads to magnetic ordering in , contrasting with the paramagnetic behavior of compounds.