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    Magnetism and correlated electrons in LaCr2Ge2N

    Jiao-Jiao Meng1,2,*, Yu-Sen Xiao3,4,*, Gen Li1,5,*, Shao-Hua Liu1, Bai-Zhuo Li1, Hao Jiang6, Zhen Yu1, Yi-Qiang Lin2, Xin-Yu Zhao2 et al.

    Qing-Chen Duan4, Wu-Zhang Yang7, Chong-Yao Zhao1, Zhi Ren7, Yu-Xue Mei1, Yong-Liang Chen3, Rui-Dan Zhong4, Qing-Xin Dong5, Peng-Tao Yang5, Shu-Gang Tan1, Bo-Sen Wang5, Huiqian Luo5, Jin-Guang Cheng5, Xue Ming1, Cao Wang1,2,†, and Guang-Han Cao2

    • *These authors contributed equally to this work.
    • †Contact author: wangcao@sdut.edu.cn

    Phys. Rev. B 112, 235164 – Published 23 December, 2025

    DOI: https://doi.org/10.1103/2twh-qbdn

    Abstract

    We report the synthesis, structure, and physical properties of a new quaternary nitride LaCr2Ge2N. The compound crystallizes in the CeCr2Si2C-type structure (P4/mmm), featuring distinctive Cr2N square sheets within Cr2Ge2N block layers. Physical characterizations reveal enhanced electron correlations evidenced by a Sommerfeld coefficient substantially larger than band calculations and pressure-induced deviation from Fermi-liquid behavior. Magnetic measurements show short-range antiferromagnetic correlations developing around 460 K, followed by long-range magnetic ordering at 14 K. Additionally, subtle anomalies at 378 K suggest possible electronic ordering. First-principles calculations reveal nearly flat Cr-3d bands near the Fermi level and predict a striped antiferromagnetic ground state. This work demonstrates how electron count variation in the CeCr2Si2C-type structure family leads to magnetic ordering in LaCr2Ge2N, contrasting with the paramagnetic behavior of LnCr2Si2C compounds.

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