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Correlated phases in rhombohedral multilayer graphene
Phys. Rev. B 113, 035132 – Published 16 January, 2026
DOI: https://doi.org/10.1103/2q6v-4brs
Abstract
We investigate the emergence of correlated electron phases in rhombohedral -layer graphene due to two-valley Coulomb interactions within a low-energy framework. Analytical expressions for Lindhard susceptibilities in intra- and intervalley channels are derived, and the critical temperatures for phase transitions are estimated using both the random phase approximation (RPA) and the parquet approximation (PA). Within RPA, only Stoner and intervalley coherent (IVC) phases are supported, while the PA reveals a richer phase structure including particle-particle (PP) channel instabilities. We establish a general scaling law for the critical temperature with respect to layer number , highlighting an upper bound as , and demonstrate a nonmonotonic decrease of the critical temperature with increasing chemical potential. The PA uncovers the role of interaction symmetry: -symmetric interactions favor intervalley Stoner order in the density channel, whereas -symmetric interactions permit a broader set of phases. A crossover in the dominant instability occurs in the particle-hole channel at a critical layer number, suggesting the emergence of magnetic or IVC phases in thicker systems. We also identify conditions under which pair-density wave (PDW) order could form in the PP channel, though its physical realization may be constrained.
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References (82)
- H. Zhou, T. Xie, A. Ghazaryan, T. Holder, J. R. Ehrets, E. M. Spanton, T. Taniguchi, K. Watanabe, E. Berg, M. Serbyn, and A. F. Young, Half- and quarter-metals in rhombohedral trilayer graphene, Nature (London) 598, 429 (2021).
- H. Zhou, T. Xie, T. Taniguchi, K. Watanabe, and A. F. Young, Superconductivity in rhombohedral trilayer graphene, Nature (London) 598, 434 (2021).
- D. Pierucci, H. Sediri, M. Hajlaoui, J.-C. Girard, T. Brumme, M. Calandra, E. Velez-Fort, G. Patriarche, M. G. Silly, G. Ferro, V. Soulière, M. Marangolo, F. Sirotti, F. Mauri, and A. Ouerghi, Evidence for flat bands near the Fermi level in epitaxial rhombohedral multilayer graphene, ACS Nano 9, 5432 (2015).
- Y. Shi, S. Xu, Y. Yang, S. Slizovskiy, S. V. Morozov, S.-K. Son, S. Ozdemir, C. Mullan, J. Barrier, J. Yin, A. I. Berdyugin, B. A. Piot, T. Taniguchi, K. Watanabe, V. I. Fal'ko, K. S. Novoselov, A. K. Geim, and A. Mishchenko, Electronic phase separation in multilayer rhombohedral graphite, Nature (London) 584, 210 (2020).
- C. R. Dean, L. Wang, P. Maher, C. Forsythe, F. Ghahari, Y. Gao, J. Katoch, M. Ishigami, P. Moon, M. Koshino, T. Taniguchi, K. Watanabe, K. L. Shepard, J. Hone, and P. Kim, Hofstadter's butterfly and the fractal quantum Hall effect in moiré superlattices, Nature (London) 497, 598 (2013).
- Y. Kim, P. Herlinger, P. Moon, M. Koshino, T. Taniguchi, K. Watanabe, and J. H. Smet, Charge inversion and topological phase transition at a twist angle induced Van Hove singularity of bilayer graphene, Nano Lett. 16, 5053 (2016).
- Y. Cao, V. Fatemi, S. Fang, K. Watanabe, T. Taniguchi, E. Kaxiras, and P. Jarillo-Herrero, Unconventional superconductivity in magic-angle graphene superlattices, Nature (London) 556, 43 (2018).
- Y. Cao, V. Fatemi, A. Demir, S. Fang, S. L. Tomarken, J. Y. Luo, J. D. Sanchez-Yamagishi, K. Watanabe, T. Taniguchi, E. Kaxiras, R. C. Ashoori, and P. Jarillo-Herrero, Correlated insulator behavior at half-filling in magic-angle graphene superlattices, Nature (London) 556, 80 (2018).
- G. Li, A. Luican, J. M. B. L. dos Santos, A. H. C. Neto, A. Reina, J. Kong, and E. Y. Andrei, Observation of Van Hove singularities in twisted graphene layers, Nat. Phys. 6, 109 (2010).
- F. Zhang, B. Sahu, H. Min, and A. H. MacDonald, Band structure of -stacked graphene trilayers, Phys. Rev. B 82, 035409 (2010).
- W. Wang, Y. Shi, A. A. Zakharov, M. Syväjärvi, R. Yakimova, R. I. G. Uhrberg, and J. Sun, Flat-band electronic structure and interlayer spacing influence in rhombohedral four-layer graphene, Nano Lett. 18, 5862 (2018).
- H. Zhou, L. Holleis, Y. Saito, L. Cohen, W. Huynh, C. L. Patterson, F. Yang, T. Taniguchi, K. Watanabe, and A. F. Young, Isospin magnetism and spin-polarized superconductivity in Bernal bilayer graphene, Science 375, 774 (2022).
- Y. Zhang, R. Polski, A. Thomson, É. Lantagne-Hurtubise, C. Lewandowski, H. Zhou, K. Watanabe, T. Taniguchi, J. Alicea, and S. Nadj-Perge, Enhanced superconductivity in spin–orbit proximitized bilayer graphene, Nature (London) 613, 268 (2023).
- A. M. Seiler, F. R. Geisenhof, F. Winterer, K. Watanabe, T. Taniguchi, T. Xu, F. Zhang, and R. T. Weitz, Quantum cascade of correlated phases in trigonally warped bilayer graphene, Nature (London) 608, 298 (2022).
- Y. Cao, Rhombohedral graphene goes correlated at four or five layers, Nat. Nanotechnol. 19, 139 (2023).
- K. Liu, J. Zheng, Y. Sha, B. Lyu, F. Li, Y. Park, Y. Ren, K. Watanabe, T. Taniguchi, J. Jia, W. Luo, Z. Shi, J. Jung, and G. Chen, Spontaneous broken-symmetry insulator and metals in tetralayer rhombohedral graphene, Nat. Nanotechnol. 19, 188 (2023).
- T. Han, Z. Lu, G. Scuri, J. Sung, J. Wang, T. Han, K. Watanabe, T. Taniguchi, H. Park, and L. Ju, Correlated insulator and Chern insulators in pentalayer rhombohedral-stacked graphene, Nat. Nanotechnol. 19, 181 (2023).
- T. Han, Z. Lu, Z. Hadjri, L. Shi, Z. Wu, W. Xu, Y. Yao, A. A. Cotten, O. Sharifi Sedeh, H. Weldeyesus, J. Yang, J. Seo, S. Ye, M. Zhou, H. Liu, G. Shi, Z. Hua, K. Watanabe, T. Taniguchi, P. Xiong, et al., Signatures of chiral superconductivity in rhombohedral graphene, Nature (London) 643, 654 (2025).
- J. Yang, X. Shi, S. Ye, C. Yoon, Z. Lu, V. Kakani, T. Han, J. Seo, L. Shi, K. Watanabe, T. Taniguchi, F. Zhang, and L. Ju, Impact of spin-orbit coupling on superconductivity in rhombohedral graphene, Nat. Mater. 24, 1058 (2025).
- T. Han, Z. Lu, Y. Yao, J. Yang, J. Seo, C. Yoon, K. Watanabe, T. Taniguchi, L. Fu, F. Zhang, and L. Ju, Large quantum anomalous Hall effect in spin-orbit proximitized rhombohedral graphene, Science 384, 647 (2024).
- F. Winterer, F. R. Geisenhof, N. Fernandez, A. M. Seiler, F. Zhang, and R. T. Weitz, Ferroelectric and spontaneous quantum Hall states in intrinsic rhombohedral trilayer graphene, Nat. Phys. 20, 422 (2024).
- W. Zhou, J. Ding, J. Hua, L. Zhang, K. Watanabe, T. Taniguchi, W. Zhu, and S. Xu, Layer-polarized ferromagnetism in rhombohedral multilayer graphene, Nat. Commun. 15, 2597 (2024).
- T. Han, Z. Lu, G. Scuri, J. Sung, J. Wang, T. Han, K. Watanabe, T. Taniguchi, L. Fu, H. Park, and L. Ju, Orbital multiferroicity in pentalayer rhombohedral graphene, Nature (London) 623, 41 (2023).
- A. M. Seiler, Y. Zhumagulov, K. Zollner, C. Yoon, D. Urbaniak, F. R. Geisenhof, K. Watanabe, T. Taniguchi, J. Fabian, F. Zhang, and R. T. Weitz, Layer-selective spin-orbit coupling and strong correlation in bilayer graphene, 2D Mater. 12, 035009 (2025).
- J. Xie, Z. Huo, X. Lu, Z. Feng, Z. Zhang, W. Wang, Q. Yang, K. Watanabe, T. Taniguchi, K. Liu, Z. Song, X. C. Xie, J. Liu, and X. Lu, Tunable fractional Chern insulators in rhombohedral graphene superlattices, Nat. Mater. 24, 1042 (2025).
- M. Christos, P. M. Bonetti, and M. S. Scheurer, Finite-momentum pairing and superlattice superconductivity in valley-imbalanced rhombohedral graphene, arXiv:2503.15471.
- Z. Dong, M. Davydova, O. Ogunnaike, and L. Levitov, Isospin- and momentum-polarized orders in bilayer graphene, Phys. Rev. B 107, 075108 (2023).
- Z. Dong, A. V. Chubukov, and L. Levitov, Transformer spin-triplet superconductivity at the onset of isospin order in bilayer graphene, Phys. Rev. B 107, 174512 (2023).
- C. Huang, T. M. R. Wolf, W. Qin, N. Wei, I. V. Blinov, and A. H. MacDonald, Spin and orbital metallic magnetism in rhombohedral trilayer graphene, Phys. Rev. B 107, L121405 (2023).
- S. A. Murshed and B. Roy, Nodal pair density waves from a quarter-metal in crystalline graphene multilayers, Phys. Rev. B 112, 085121 (2025).
- A. L. Szabó and B. Roy, Competing orders and cascade of degeneracy lifting in doped Bernal bilayer graphene, Phys. Rev. B 105, L201107 (2022).
- X. Mu and J. Zhou, Valley-dependent giant orbital moments and transport features in rhombohedral graphene multilayers, Phys. Rev. B 111, 165102 (2025).
- Y.-Z. Chou, J. Zhu, and S. Das Sarma, Intravalley spin-polarized superconductivity in rhombohedral tetralayer graphene, Phys. Rev. B 111, 174523 (2025).
- R. D. Mayrhofer and A. V. Chubukov, Valley- and spin-polarized states in Bernal bilayer graphene, Phys. Rev. B 111, 245114 (2025).
- Z. Liu and J. Wang, Layer-dependent quantum anomalous Hall effect in rhombohedral graphene, Phys. Rev. B 111, L081111 (2025).
- N. B. Kopnin, Surface superconductivity in multilayered rhombohedral graphene: Supercurrent, JETP Lett. 94, 81 (2011).
- J. H. Muten, A. J. Copeland, and E. McCann, Exchange interaction, disorder, and stacking faults in rhombohedral graphene multilayers, Phys. Rev. B 104, 035404 (2021).
- K. Huang, S. Das Sarma, and X. Li, Fractional quantum anomalous Hall effect in rhombohedral multilayer graphene with a strong displacement field, Phys. Rev. B 111, 075130 (2025).
- Z. Dong, A. S. Patri, and T. Senthil, Theory of quantum anomalous Hall phases in pentalayer rhombohedral graphene moiré structures, Phys. Rev. Lett. 133, 206502 (2024).
- A. L. Szabó and B. Roy, Metals, fractional metals, and superconductivity in rhombohedral trilayer graphene, Phys. Rev. B 105, L081407 (2022).
- W. Qin, C. Huang, T. Wolf, N. Wei, I. Blinov, and A. H. MacDonald, Functional renormalization group study of superconductivity in rhombohedral trilayer graphene, Phys. Rev. Lett. 130, 146001 (2023).
- D.-C. Lu, T. Wang, S. Chatterjee, and Y.-Z. You, Correlated metals and unconventional superconductivity in rhombohedral trilayer graphene: A renormalization group analysis, Phys. Rev. B 106, 155115 (2022).
- Y. Zhumagulov, D. Kochan, and J. Fabian, Emergent correlated phases in rhombohedral trilayer graphene induced by proximity spin-orbit and exchange coupling, Phys. Rev. Lett. 132, 186401 (2024).
- Y. Zhumagulov, D. Kochan, and J. Fabian, Swapping exchange and spin-orbit induced correlated phases in proximitized Bernal bilayer graphene, Phys. Rev. B 110, 045427 (2024).
- Z. Dong and L. Levitov, Chiral Stoner magnetism in Dirac bands, Phys. Rev. B 110, 104420 (2024).
- Z. M. Raines and A. V. Chubukov, Two-dimensional Stoner transitions beyond mean field, Phys. Rev. B 110, 235433 (2024).
- Z. Dong, L. Levitov, and A. V. Chubukov, Superconductivity near spin and valley orders in graphene multilayers, Phys. Rev. B 108, 134503 (2023).
- D. V. Chichinadze, L. Classen, and A. V. Chubukov, Nematic superconductivity in twisted bilayer graphene, Phys. Rev. B 101, 224513 (2020).
- D. V. Chichinadze, L. Classen, Y. Wang, and A. V. Chubukov, Symmetry in twisted bilayer graphene: An itinerant perspective, Phys. Rev. Lett. 128, 227601 (2022).
- T. E. Beechem, T. Ohta, B. Diaconescu, and J. T. Robinson, Rotational disorder in twisted bilayer graphene, ACS Nano 8, 1655 (2014).
- A. Uri, S. Grover, Y. Cao, J. A. Crosse, K. Bagani, D. Rodan-Legrain, Y. Myasoedov, K. Watanabe, T. Taniguchi, P. Moon, M. Koshino, P. Jarillo-Herrero, and E. Zeldov, Mapping the twist-angle disorder and Landau levels in magic-angle graphene, Nature (London) 581, 47 (2020).
- A. C. Gadelha, D. A. A. Ohlberg, F. C. Santana, G. S. N. Eliel, J. S. Lemos, V. Ornelas, D. Miranda, R. B. Nadas, K. Watanabe, T. Taniguchi, C. Rabelo, P. P. de Mello Venezuela, G. Medeiros-Ribeiro, A. Jorio, L. G. Cançado, and L. C. Campos, Twisted bilayer graphene: A versatile fabrication method and the detection of variable nanometric strain caused by twist-angle disorder, ACS Appl. Nano Mater. 4, 1858 (2021).
- J. H. Wilson, Y. Fu, S. Das Sarma, and J. H. Pixley, Disorder in twisted bilayer graphene, Phys. Rev. Res. 2, 023325 (2020).
- N. P. Kazmierczak, M. V. Winkle, C. Ophus, K. C. Bustillo, S. Carr, H. G. Brown, J. Ciston, T. Taniguchi, K. Watanabe, and D. K. Bediako, Strain fields in twisted bilayer graphene, Nat. Mater. 20, 956 (2021).
- N. Nakatsuji and M. Koshino, Moiré disorder effect in twisted bilayer graphene, Phys. Rev. B 105, 245408 (2022).
- R. Samajdar and M. S. Scheurer, Microscopic pairing mechanism, order parameter, and disorder sensitivity in moiré superlattices: Applications to twisted double-bilayer graphene, Phys. Rev. B 102, 064501 (2020).
- G. Shavit, K. Kolář, C. Mora, F. von Oppen, and Y. Oreg, Strain disorder and gapless intervalley coherent phase in twisted bilayer graphene, Phys. Rev. B 107, L081403 (2023).
- O. A. Awoga, T. Löthman, and A. M. Black-Schaffer, Superconductivity and magnetism in the surface states of ABC-stacked multilayer graphene, Phys. Rev. B 108, 144504 (2023).
- L. B. Braz, T. Nag, and A. M. Black-Schaffer, Competing magnetic states on the surface of multilayer ABC-stacked graphene, Phys. Rev. B 110, L241401 (2024).
- A. Fischer, L. Klebl, D. M. Kennes, and T. O. Wehling, Supercell Wannier functions and a faithful low-energy model for Bernal bilayer graphene, Phys. Rev. B 110, L201113 (2024).
- E. McCann and M. Koshino, The electronic properties of bilayer graphene, Rep. Prog. Phys. 76, 056503 (2013).
- M. Nakamura and L. Hirasawa, Electric transport and magnetic properties in multilayer graphene, Phys. Rev. B 77, 045429 (2008).
- G. Rohringer, H. Hafermann, A. Toschi, A. A. Katanin, A. E. Antipov, M. I. Katsnelson, A. I. Lichtenstein, A. N. Rubtsov, and K. Held, Diagrammatic routes to nonlocal correlations beyond dynamical mean field theory, Rev. Mod. Phys. 90, 025003 (2018).
- G. Rohringer, A. Valli, and A. Toschi, Local electronic correlation at the two-particle level, Phys. Rev. B 86, 125114 (2012).
- D. Sénéchal, A.-M. S. Tremblay, and C. Bourbonnais, Theoretical Methods for Strongly Correlated Electrons (Springer, New York, NY, 2004), p. 362.
- J. C. Slonczewski and P. R. Weiss, Band structure of graphite, Phys. Rev. 109, 272 (1958).
- J. W. McClure, Theory of diamagnetism of graphite, Phys. Rev. 119, 606 (1960).
- J. W. McClure, Band structure of graphite and de Haas–van Alphen effect, Phys. Rev. 108, 612 (1957).
- R. Côté and M. Barrette, Validity of the two-component model of bilayer and trilayer graphene in a magnetic field, Phys. Rev. B 88, 245445 (2013).
- M. Koshino and E. McCann, Trigonal warping and Berry's phase in ABC-stacked multilayer graphene, Phys. Rev. B 80, 165409 (2009).
- T. Takimoto, T. Hotta, and K. Ueda, Strong-coupling theory of superconductivity in a degenerate Hubbard model, Phys. Rev. B 69, 104504 (2004).
- K. Kubo, Pairing symmetry in a two-orbital Hubbard model on a square lattice, Phys. Rev. B 75, 224509 (2007).
- C. C. Nishi, Simple derivation of general Fierz-type identities, Am. J. Phys. 73, 1160 (2005).
- N. Witt, E. G. C. P. van Loon, T. Nomoto, R. Arita, and T. O. Wehling, Efficient fluctuation-exchange approach to low-temperature spin fluctuations and superconductivity: From the Hubbard model to , Phys. Rev. B 103, 205148 (2021).
- M. Schüler, M. Rösner, T. O. Wehling, A. I. Lichtenstein, and M. I. Katsnelson, Optimal Hubbard models for materials with nonlocal Coulomb interactions: Graphene, silicene, and benzene, Phys. Rev. Lett. 111, 036601 (2013).
- S. Käser, H. U. R. Strand, N. Wentzell, A. Georges, O. Parcollet, and P. Hansmann, Interorbital singlet pairing in : A Hund's superconductor, Phys. Rev. B 105, 155101 (2022).
- T. O. Wehling, E. Şaşıoğlu, C. Friedrich, A. I. Lichtenstein, M. I. Katsnelson, and S. Blügel, Strength of effective Coulomb interactions in graphene and graphite, Phys. Rev. Lett. 106, 236805 (2011).
- A. B. Kuzmenko, I. Crassee, D. van der Marel, P. Blake, and K. S. Novoselov, Determination of the gate-tunable band gap and tight-binding parameters in bilayer graphene using infrared spectroscopy, Phys. Rev. B 80, 165406 (2009).
- R. D. Mayrhofer, M. Schoenzeit, and A. V. Chubukov, Stoner transition at finite temperature in a two-dimensional isotropic Fermi liquid, Phys. Rev. B 112, 165128 (2025).
- S. Hörhold, J. Graf, M. Marganska, and M. Grifoni, Two-bands Ising superconductivity from Coulomb interactions in monolayer , 2D Mater. 10, 025008 (2023).
- A. Herasymchuk, S. G. Sharapov, O. V. Yazyev, and Y. Zhumagulov, Correlated phases in rhombohedral multilayer graphene—Data and code release (v1.0.0), Zenodo (2025), doi: 10.5281/zenodo.17980837.
- K. Zollner, M. Gmitra, and J. Fabian, Proximity spin-orbit and exchange coupling in ABA and ABC trilayer graphene van der Waals heterostructures, Phys. Rev. B 105, 115126 (2022).