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    Spectroscopy and transport of nonpolarons in silicon and germanium: Influence of doping and temperature

    Raveena Gupta1, Joao Abreu1, and Matthieu J. Verstraete1,2,*

    • *Contact author: matthieu.verstraete@uliege.be

    Phys. Rev. B 113, 014312 – Published 20 January, 2026

    DOI: https://doi.org/10.1103/22ps-4f7n

    Abstract

    We perform a first-principles investigation of electron-phonon interactions in silicon and germanium, uncovering distinct nonpolaronic spectral and transport fingerprints in these archetypal covalent semiconductors. Using many-body perturbation theory with the retarded cumulant expansion, we compute quasiparticle energies, lifetimes, and phonon satellites beyond the Dyson-Migdal approximation. Short-range crystal fields dominate coupling in both materials, yet their low-temperature spectral fingerprints differ: Si exhibits well-resolved satellites at both band edges, whereas Ge displays strong sidebands mainly at the valence-band maximum (VBM) and much weaker features at the conduction-band minimum (CBM). Phonon-induced satellites in both materials broaden and merge with the quasiparticle peak at elevated temperatures. Doping broadens peaks and compresses satellite-quasiparticle separation, with n-type carriers affecting the CBM and p-type the VBM. Mobility calculations, combining cumulant-derived phonon scattering with experimentally motivated ionized-impurity scattering models, reproduce measured trends and reveal Ge's consistently higher mobilities than Si, stemming from lighter effective masses and weaker coupling. These results link band-edge asymmetries and phonon energetics to measurable transport differences, providing a unified framework for predicting mobility in nonpolar semiconductors.

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