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Doping-induced nematic and stripe orders within the charge density wave state of TiSe2

Daniel Muñoz-Segovia1,2,*, Jörn W. F. Venderbos3,4, Adolfo G. Grushin5, and Fernando de Juan1,6,†

  • *Contact author: dm3886@columbia.edu
  • †Contact author: fernando.dejuan@dipc.org

Phys. Rev. B 112, 165119 – Published 14 October, 2025

DOI: https://doi.org/10.1103/1nxh-3v88

Abstract

In this work, we present a theory to address conflicting experimental claims regarding the charge density wave (CDW) state in TiSe2, including whether there is single or multiple CDW transitions and whether threefold rotation symmetry (C3) is broken. Using a continuum k·p model coupled to the CDW order parameter, we show how commonplace conduction band doping induces a nematic transition from a C3-symmetric 3Q CDW to a C3-breaking 3Q CDW, which is favored by the large ellipticity of the conduction bands of TiSe2. We also find that a 1Q stripe CDW is generically stabilized for sufficiently high electron doping. We then show how both stripe and nematic CDW states emerge self-consistently from a minimal interacting tight-binding model for both positive and negative initial gaps. Our theory provides a scenario in which, as temperature is lowered, a second C3-breaking transition may occur or not, depending on the doping level, potentially explaining the experimental variability. These predictions can be further verified with a variety of probes including transport, photoemission, and tunneling.

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