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    Orbital-selective band structure evolution in BaFe2−xMxAs2 (M = Cr, Co, Cu, Ru, and Mn) probed by polarization-dependent ARPES

    K. R. Pakuszewski1, M. R. Cantarino2, I. Romanenko1, A. P. Machado3, M. M. Piva4, G. S. Freitas3,5, H. B. Pizzi3, F. A. Garcia6, P. G. Pagliuso3 et al.

    C. Adriano1

    Phys. Rev. B 113, 245101 – Published 1 June, 2026

    DOI: https://doi.org/10.1103/1856-p1fr

    Abstract

    We present a systematic study of the evolution of the band structure in the Fe-based superconductor family BaFe2−xMxAs2 (M = Co, Cu, Cr, Ru, and Mn) using polarization-dependent angle-resolved photoemission spectroscopy (ARPES). Low-substituted samples, with comparable spin-density wave transition temperatures (TSDW), were chosen to enable controlled comparisons with respect to the parent compound. The sizes of the central α and β hole pockets remain largely unchanged across different substitutions, while the γ pocket exhibits no clear correlation with either TSDW or the As height relative to the Fe plane. The evolution of both hole and electron pockets does not follow a rigid-band shift scenario and shows no systematic dependence on the nominal electron or hole character of the substituting element. However, subtle trends are observed: a modest increase of the electron pocket with planar character that correlates with TSDW suppression, while its contraction appears linked to an increase in the As height relative to the Fe planes. Our results suggest that the suppression of TSDW is primarily driven by changes in the Fe–As bond length, with the effect being more pronounced in electronic states with planar character. These findings provide insight into the electronic structure of BaFe2−xMxAs2.

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