- Editors' Suggestion
- Letter
Confinement-driven renormalization of magnon and phonon spectra in nanoparticles
Phys. Rev. B 112, L140406 – Published 23 October, 2025
DOI: https://doi.org/10.1103/15zz-8g6x
Abstract
Magnetite () nanoparticles exhibit size-dependent magnetic and thermal properties crucial for spintronics, thermoelectrics, and hyperthermia applications, yet the nanoscale behavior of magnons and phonons remains poorly understood. Combining time-of-flight inelastic neutron scattering and numerical simulations, we reveal a universal mechanism of confinement-driven quasiparticle renormalization in nanoparticles. In 8-nm particles, optical phonons soften by 0.5 meV and significantly broaden, while acoustic magnons exhibit suppressed group velocities (from to ) due to surface-induced exchange disorder. Heterogeneous spin environments, combining bulklike () and surfacelike () interactions, quantitatively explain spectral broadening and magnon softening. These findings establish finite-size confinement as a general paradigm for engineering spin and thermal transport in nanoscale systems, with direct implications for enhancing spin-wave lifetimes in spintronic devices and phonon engineering in thermoelectrics.