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Confinement-driven renormalization of magnon and phonon spectra in Fe3O4 nanoparticles

Kyle A. Portwin1,2,*, Pablo Galaviz3, David L. Cortie2,3, Dehong Yu3, Kirrily C. Rule2,3,†, and Zhenxiang Cheng1,‡

  • 1Institute for Superconducting and Electronic Materials, Faculty of Engineering and Information Science, University of Wollongong, Innovation Campus, Squires Way, North Wollongong, New South Wales 2500, Australia
  • 2School of Physics, Faculty of Engineering and Information Science, University of Wollongong, Northfields Avenue, Wollongong, New South Wales 2522, Australia
  • 3Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights, New South Wales 2234, Australia

  • *Contact author: kyleportwin@gmail.com
  • †Contact author: kirrily@ansto.gov.au
  • ‡Contact author: cheng@uow.edu.au

Phys. Rev. B 112, L140406 – Published 23 October, 2025

DOI: https://doi.org/10.1103/15zz-8g6x

Abstract

Magnetite (Fe3O4) nanoparticles exhibit size-dependent magnetic and thermal properties crucial for spintronics, thermoelectrics, and hyperthermia applications, yet the nanoscale behavior of magnons and phonons remains poorly understood. Combining time-of-flight inelastic neutron scattering and numerical simulations, we reveal a universal mechanism of confinement-driven quasiparticle renormalization in Fe3O4 nanoparticles. In 8-nm particles, optical phonons soften by 0.5 meV and significantly broaden, while acoustic magnons exhibit suppressed group velocities (from 14000ms−1 to 10000ms−1) due to surface-induced exchange disorder. Heterogeneous spin environments, combining bulklike (J) and surfacelike (J′<J) interactions, quantitatively explain spectral broadening and magnon softening. These findings establish finite-size confinement as a general paradigm for engineering spin and thermal transport in nanoscale systems, with direct implications for enhancing spin-wave lifetimes in spintronic devices and phonon engineering in thermoelectrics.

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