Origin of the enhanced Curie temperature in monolayer over
Phys. Rev. B 113, 064438 – Published 25 February, 2026
DOI: https://doi.org/10.1103/12lg-69kk
Abstract
The origin of the remarkable Curie temperature () enhancement in monolayer (FGaT, ∼ 240 K) relative to isostructural (FGeT, ∼ 130 K) remains unresolved. Here, we employ a combined energy mapping + spin spiral approach to disentangle competing intralayer and interlayer exchange interactions in (FXT, ,Ga). Our results reveal that FGaT's significant enhancement arises from a weakened intralayer antiferromagnetic coupling within the outer layer concurrent with a strengthened interlayer ferromagnetic coupling between and the middle layer. Meanwhile, we quantitatively separate the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction from isotropic exchange mechanisms, revealing attenuation in both intralayer RKKY coupling and superexchange interactions. Furthermore, we identify strain as tuning knobs for improving the of the sublattice, providing quantitative design principles for achieving room-temperature magnets. These findings resolve persistent questions on the origin of enhancement while establishing rational design strategies for novel two-dimensional magnetic materials.