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    Origin of the enhanced Curie temperature in monolayer Fe3GaTe2 over Fe3GeTe2

    Bingjie Liu1,2, Can Huang3, Lingzi Jiang1,2, Yanfei Pan1,2, Chunlan Ma3,*, Jiyu Fan1,2,†, and Yan Zhu1,2,‡

    • *Contact author: wlxmcl@mail.usts.edu.cn
    • †Contact author: jiyufan@nuaa.edu.cn
    • ‡Contact author: yzhu@nuaa.edu.cn

    Phys. Rev. B 113, 064438 – Published 25 February, 2026

    DOI: https://doi.org/10.1103/12lg-69kk

    Abstract

    The origin of the remarkable Curie temperature (Tc) enhancement in monolayer Fe3GaTe2 (FGaT, Tc ∼ 240 K) relative to isostructural Fe3GeTe2 (FGeT, Tc ∼ 130 K) remains unresolved. Here, we employ a combined energy mapping + spin spiral approach to disentangle competing intralayer and interlayer exchange interactions in Fe3XTe2 (FXT, X=Ge,Ga). Our results reveal that FGaT's significant Tc enhancement arises from a weakened intralayer antiferromagnetic coupling within the outer Fea layer concurrent with a strengthened interlayer ferromagnetic coupling between Fea and the middle Feb layer. Meanwhile, we quantitatively separate the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction from isotropic exchange mechanisms, revealing attenuation in both intralayer Fea−Fea RKKY coupling and superexchange interactions. Furthermore, we identify strain as tuning knobs for improving the Tc of the Fea sublattice, providing quantitative design principles for achieving room-temperature magnets. These findings resolve persistent questions on the origin of Tc enhancement while establishing rational design strategies for novel two-dimensional magnetic materials.

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