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Quasipolaron Surface Polarization in Bismuth Ferrite

Jiarui Zhang1, Yongbao Cui2, Nannan Liu3, Qi Qi1, Rui Huang1, Kai Chen1,4,*, Laijun Liu2,†, Zhida Han5,‡, and Guoliang Yuan3

  • 1School of Science, Nanjing University of Science and Technology, Nanjing 210094, People’s Republic of China
  • 2Guilin University of Technology, Guilin 541004, People’s Republic of China
  • 3School of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210094, People’s Republic of China
  • 4MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing, Nanjing University of Science and Technology, Nanjing 210094, People’s Republic of China
  • 5School of Electronic and Information Engineering, Changshu Institute of Technology, Changshu 215500, People’s Republic of China

  • *kai@njust.edu.cn
  • †ljliu@163.com
  • ‡han @cslg.edu.cn

Phys. Rev. Applied 18, L051002 – Published 8 November, 2022

DOI: https://doi.org/10.1103/PhysRevApplied.18.L051002

Abstract

With the introduction of a not fully screened polarization that leads to three magnetic subdomains nested in one ferroelectric domain, we identify it as the quasipolaron surface polarization in the electrode effect of bismuth ferrite. The remanent polarization at 40 Hz is about 439 μC/cm2 in the dielectric hysteresis loop of a reverse S shape, accompanying the antiferromagnetic one of an S shape, which reveals that the surface is an indispensable part in spintronics.

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References (17)

  1. Aurore Finco, Angela Haykal, Stéphane Fusil, Pawan Kumar, Pauline Dufour, Anne Forget, Dorothée Colson, Jean-Yves Chauleau, Michel Viret, Nicolas Jaouen, Vincent Garcia, and Vincent Jacques, Imaging Topological Defects in a Noncollinear Antiferromagnet, Phys. Rev. Lett. 128, 187201 (2022).
  2. A. Palewicz, P. Rrzenioslo, I. Sosonowska, and A. W. Hewat, Atomic displacements in BiFeO3 as a function of temperature: Neutron diffraction study, Acta Crystallogr. Sect. B 63, 537 (2007).
  3. S. Chattopadhyay, S. D. Kelly, V. R. Palkar, L. Fan, and C. U. Segre, Investigation of size effects in magnetoelectric BiFeO3, Phys. Scr. T115, 709 (2005).
  4. R. Saeterli, S. M. Selbah, P. Ravindran, T. Grande, and R. Holmestad, Electronic structure of multiferroic BiFeO3 and related compounds: Electron energy loss spectroscopy and density functional study, Phys. Rev. B 82, 064102 (2010).
  5. D. Ricinschi, K.-Y. Yun, and M. Okuyama, A mechanism for the 150 µC/cm-2 polarization of BiFeO3 films based on first-principles calculations and new structural data, J. Phys.: Condens. Matter 18, L97 (2006).
  6. I.-T. Bae, A. Kovacs, H. J. Zhao, J. Iniguez, Sh. Yasui, T. Ichinose, and H. Naganuma, Elucidation of crystal and electronic structures within highly strained BiFeO3 by transmission electron microscopy and first-principles simulation, Sci. Rep. 7, 46498 (2017).
  7. Grégory Geneste, Charles Paillard, and Brahim Dkhil, Polarons, vacancies, vacancy associations, and defect states in multiferroic BiFeO3, Phys. Rev. B 99, 024104 (2019).
  8. J. T. Han, Y.-H. Huang, X.-J. Wu, C.-L. Wu, W. Wei, B. Peng, W. Huang, and J. B. Goodenough, Tunable synthesis of bismuth ferrites with various morphologies, Adv. Mater. 18, 2145 (2006).
  9. S. V. Kiselev, R. P. Ozerov, and G. S. Zhdanov, Detection of magnetic order in ferroelectric BiFeO3 by neutron diffraction, Sov. Phys. Dokl. 7, 742 (1963).
  10. I. H. Lone, J. Aslam, N. R. E. Radwan, A. H. Bashal, A. F. Ajlou, and A. Ajhter, Multiferroic ABO3 transition metal oxides: A rare interaction of ferroelectricity and magnetism, Nano Res. Lett. 14, 142 (2019).
  11. Y. Yin and Q. Li, A review on all-perovskite multiferroic tunnel junctions, J. Materiomics 3, 245 (2017).
  12. R. Schmidt, J. Ventura, E. Langenberg, N. M. Nemes, C. Munuera, M. Varela, M. Garcia-Hernandez, C. Leon, and J. Santamaria, Magnetoimpedance spectroscopy of epitaxial multiferroic thin films, Phys. Rev. B 86, 035113 (2012).
  13. A. K. Jonscher, Dielectric Relaxation in Solids (Chelsea Dielectrics, London, 1983).
  14. J.-R. Zhang, Y.-Q. Li, Q.-R. Yang, Y.-W. Yang, F.-Q. Meng, T.-F. Wang, Z. Xia, Y. Wang, K. Chen, Q.-H. Zhang, et al., A structural perspective on giant permittivity CaCu3Ti4O12: One way to quantum dielectric physics in solids, Open Ceram. 6, 100126 (2021).
  15. P. W. Anderson, New approach to the theory of superexchange interactions, Phys. Rev. 115, 2 (1959).
  16. Y. Shen, X.-G. Wan, Q.-B. Zhao, G. Li, and C.-G. Duan, Non-d0 ferroelectricity from semicovalent superexchange in bismuth ferrite, Phys. Rev. B 104, 024421 (2021).
  17. J. F. Scott, Ferroelectrics go bananas, J. Phys.: Condens. Matter 20, 021001 (2008).

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