Memristive behavior in self-assembled carbon quantum dot structures formed via evaporation-induced self-assembly
Phys. Rev. Applied 24, 064063 – Published 24 December, 2025
DOI: https://doi.org/10.1103/7cb1-5kxj
Abstract
Memristors are emerging components in neuromorphic computing due to their ability to retain memory through resistive switching. In this work, we report the fabrication and characterization of low-cost memristive devices based on self-assembled structures of carbon quantum dots (CQDs). These structures were produced via evaporation-induced self-assembly of CQDs dispersed in water, deposited on silicon substrates at controlled low temperatures. Morphological analysis revealed that drying temperature plays a critical role in the resulting spatial configurations, with temperatures around yielding elongated, millimeter-scale wirelike structures that suppress the typical coffee-ring effect. Electrical characterization of these structures showed pronounced hysteresis in the current-voltage curve, indicative of memristive behavior. Further analysis confirmed space-charge-limited conduction as the dominant transport mechanism, and transient current response supported the participation of oxygen-containing functional groups in charge trapping and release. These findings demonstrate that self-assembled structures of CQDs can act as effective memristors, offering a scalable and biocompatible platform for future applications in neuromorphic systems and flexible memory technologies.